A novel efficient method for the synthesis of substituted olefins; cross coupling of two different alcohols using NaHSO4/SiO2

2013 ◽  
Vol 49 (59) ◽  
pp. 6605 ◽  
Author(s):  
Tadashi Aoyama ◽  
Shuichi Koda ◽  
Yuka Takeyoshi ◽  
Tetsuhiro Ito ◽  
Toshio Takido ◽  
...  
RSC Advances ◽  
2017 ◽  
Vol 7 (45) ◽  
pp. 27974-27980 ◽  
Author(s):  
Li Ling ◽  
Jing Cao ◽  
Jianfeng Hu ◽  
Hao Zhang

An efficient method for direct N-alkylation of indoles via copper-catalyzed reductive cross coupling between N-tosylhydrazones and indoles has been developed.


Synthesis ◽  
2019 ◽  
Vol 51 (18) ◽  
pp. 3511-3519
Author(s):  
Bochao Zhou ◽  
Shiyu Guo ◽  
Zheng Fang ◽  
Zhao Yang ◽  
Chengkou Liu ◽  
...  

A new and efficient method for the synthesis of C-3 dicarbonyl indoles via oxidative cross-coupling of styrenes with indoles under metal-free conditions has been developed. Moreover, a broad scope of C-3 dicarbonyl indoles in moderate to good yields were obtained, and a plausible mechanism is proposed based on control and isotope-labeling experiments.


2020 ◽  
Vol 56 (95) ◽  
pp. 15020-15023
Author(s):  
Shuguang Zhou ◽  
Duan-Yang Liu ◽  
Suo Wang ◽  
Jie-Sheng Tian ◽  
Teck-Peng Loh

N-Substituted 2-pyridones are installed through the RhIII-catalyzed formal [3+3] annulation of enaminones with acrylates. Control and deuterated experiments led to a plausible mechanism involving C(sp2)–H bond cross-coupling and aminolysis cyclization.


2019 ◽  
Vol 6 (3) ◽  
pp. 313-318 ◽  
Author(s):  
Bing-Zhi Chen ◽  
Chuang-Xin Wang ◽  
Zhen-Hua Jing ◽  
Xue-Qiang Chu ◽  
Teck-Peng Loh ◽  
...  

An efficient method for the synthesis of alkyl indium reagents via an indium(iii) or lead(ii) halide-catalyzed direct insertion of indium into alkyl iodides is developed. NMR and ESI-MS analyses indicated the formation of a mixture of an alkyl indium dihalide (RInX2) and a dialkyl indium halide (R2InX).


2017 ◽  
Vol 15 (19) ◽  
pp. 4199-4204 ◽  
Author(s):  
P.-O. Delaye ◽  
M. Pénichon ◽  
H. Allouchi ◽  
C. Enguehard-Gueiffier ◽  
A. Gueiffier

An efficient method for regiocontrolled functionalization of 2,3-dihalogenoimidazo[1,2-a]pyridine was developed.


2015 ◽  
Vol 51 (18) ◽  
pp. 3838-3841 ◽  
Author(s):  
Jenilee D. Way ◽  
Cody Bergman ◽  
Frank Wuest

The study describes the Sonogashira cross-coupling reaction with 4-[18F]fluoroiodobenzene ([18F]FIB) as novel and efficient method for rapid labelling of peptides with the short-lived positron emitter fluorine-18.


RSC Advances ◽  
2018 ◽  
Vol 8 (61) ◽  
pp. 34883-34894 ◽  
Author(s):  
Urvashi Urvashi ◽  
Vibha Tandon ◽  
Parthasarathi Das ◽  
S. Kukreti

An efficient method to produce diarylpyrazolo[3,4-b]pyridines derivatives via combination of chemoselective Suzuki–Miyaura cross-coupling reactions has been developed.


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