Rapid one-pot propargylamine synthesis by plasmon mediated catalysis with gold nanoparticles on ZnO under ambient conditions

2013 ◽  
Vol 49 (17) ◽  
pp. 1732 ◽  
Author(s):  
María González-Béjar ◽  
Kate Peters ◽  
Geniece L. Hallett-Tapley ◽  
Michel Grenier ◽  
Juan C. Scaiano
Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1992
Author(s):  
Andrew Harrison ◽  
Christina Tang

Performing multiple reaction steps in “one pot” to avoid the need to isolate intermediates is a promising approach for reducing solvent waste associated with liquid phase chemical processing. In this work, we incorporated gold nanoparticle catalysts into polymer nanoreactors via amphiphilic block copolymer directed self-assembly. With the polymer nanoreactors dispersed in water as the bulk solvent, we demonstrated the ability to facilitate two reaction steps in one pot with spontaneous precipitation of the product from the reaction mixture. Specifically, we achieved imide synthesis from 4-nitrophenol and benzaldehyde as a model reaction. The reaction occured in water at ambient conditions; the desired 4-benzylideneaminophenol product spontaneously precipitated from the reaction mixture while the nanoreactors remained stable in dispersion. A 65% isolated yield was achieved. In contrast, PEGylated gold nanoparticles and citrate stabilized gold nanoparticles precipitated with the reaction product, which would complicate both the isolation of the product as well as reuse of the catalyst. Thus, amphiphilic nanoreactors dispersed in water are a promising approach for reducing solvent waste associated with liquid phase chemical processing by using water as the bulk solvent, eliminating the need to isolate intermediates, achieving spontaneous product separation to facilitate the recycling of the reaction mixture, and simplifying the isolation of the desired product.


2016 ◽  
Vol 3 (4) ◽  
pp. 629-637 ◽  
Author(s):  
Adriana Both Engel ◽  
Mikhael Bechelany ◽  
Olivier Fontaine ◽  
Aziz Cherifi ◽  
David Cornu ◽  
...  

2018 ◽  
Vol 2018 ◽  
pp. 1-13 ◽  
Author(s):  
Haliza Katas ◽  
Noor Zianah Moden ◽  
Chei Sin Lim ◽  
Terence Celesistinus ◽  
Jie Yee Chan ◽  
...  

Biosynthesized or biogenic metallic nanoparticles, particularly silver and gold nanoparticles (AgNPs and AuNPs, respectively), have been increasingly used because of their advantages, including high stability and loading capacity; moreover, these nanoparticles are synthesized using a green and cost-effective method. Previous studies have investigated reducing and/or stabilizing agents from various biological sources, including plants, microorganisms, and marine-derived products, using either a one-pot or a multistep process at different conditions. In addition, extensive studies have been performed to determine the biological or pharmacological effects of these nanoparticles, such as antimicrobial, antitumor, anti-inflammatory, and antioxidant effects. In the recent years, chitosan, a natural cationic polysaccharide, has been increasingly investigated as a reducing and/or stabilizing agent in the synthesis of biogenic metallic nanoparticles with potential applications in nanomedicine. Here, we have reviewed the mechanism of biosynthesis and potential applications of AgNPs and AuNPs and their chitosan-mediated nanocomposites in nanomedicine.


2017 ◽  
Vol 41 (20) ◽  
pp. 12153-12158 ◽  
Author(s):  
R. Aufaure ◽  
R. Buendia ◽  
L. Motte ◽  
J. Hardouin ◽  
Y. Lalatonne ◽  
...  

Click synthesis of pegylated bisphosphonates for one pot preparation of stable gold nanoparticles.


2019 ◽  
Vol 124 ◽  
pp. 838-845 ◽  
Author(s):  
Morgana Souza Marques ◽  
Κarine Modolon Zepon ◽  
Julia Maia Heckler ◽  
Fernando Dal Pont Morisso ◽  
Marcos Marques da Silva Paula ◽  
...  

2015 ◽  
Vol 132 ◽  
pp. 122-131 ◽  
Author(s):  
Sorina Suarasan ◽  
Monica Focsan ◽  
Olga Soritau ◽  
Dana Maniu ◽  
Simion Astilean

Sign in / Sign up

Export Citation Format

Share Document