The intramolecular nitrile oxide cycloaddition route to spirocyclic alkaloids. A total synthesis of isonitramine and sibirine

1985 ◽  
pp. 847 ◽  
Author(s):  
Alan P. Kozikowski ◽  
P.-W. Yuen
Keyword(s):  
Total Synthesis ◽  
Nitrile Oxide

Total synthesis of the potent antifungal agents bengazole C and E

2009 ◽  
Vol 74 (6) ◽  
pp. 887-900 ◽  
Author(s):  
Álvaro Enríquez-García ◽  
Steven V. Ley
Keyword(s):  
Natural Products ◽  
Antifungal Activity ◽  
Total Synthesis ◽  
Marine Natural Products ◽  
Antifungal Agents ◽  
Nitrile Oxide ◽  
Total Syntheses ◽  
Unique Structure

The bengazoles are marine natural products with unique structure, containing two oxazole rings flanking a single carbon. They show very potent antifungal activity. The total syntheses of bengazole C and E are described following a convergent route which involves diastereoselective cycloaddition of an appropriately substituted nitrile oxide with a butane-1,2-diacetal-protected alkenediol as the key step.

Furanoterpene Synthesis via Intramolecular Nitrile Oxide Cycloaddition Reaction: A Total Synthesis of (+)-Menthofuran

Heterocycles ◽  
1993 ◽  
Vol 36 (2) ◽  
pp. 345 ◽  
Author(s):  
Kozo Shishido ◽  
Koji Umimoto ◽  
Takeshi Takata ◽  
Osamu Irie ◽  
Masayuki Shibuya
Keyword(s):  
Total Synthesis ◽  
Cycloaddition Reaction ◽  
Nitrile Oxide

Total Synthesis of (+)-Pochonin D and (+)-Monocillin II via Chemo- and Regioselective Intramolecular Nitrile Oxide Cycloaddition

2017 ◽  
Vol 19 (21) ◽  
pp. 6004-6007 ◽  
Author(s):  
Hyeonjeong Choe ◽  
Hyukjoon Cho ◽  
Hyun-Jeong Ko ◽  
Jongkook Lee
Keyword(s):  
Total Synthesis ◽  
Nitrile Oxide

Remote Stereoinductive Intramolecular Nitrile Oxide Cycloaddition: Asymmetric Total Synthesis and Structure Revision of (−)-11β-Hydroxycurvularin

2016 ◽  
Vol 81 (6) ◽  
pp. 2612-2617 ◽  
Author(s):  
Hyeonjeong Choe ◽  
Thuy Trang Pham ◽  
Joo Yun Lee ◽  
Muhammad Latif ◽  
Haeil Park ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Nitrile Oxide ◽  
Asymmetric Total Synthesis ◽  
Structure Revision
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