Remote Stereoinductive Intramolecular Nitrile Oxide Cycloaddition: Asymmetric Total Synthesis and Structure Revision of (−)-11β-Hydroxycurvularin

2016 ◽  
Vol 81 (6) ◽  
pp. 2612-2617 ◽  
Author(s):  
Hyeonjeong Choe ◽  
Thuy Trang Pham ◽  
Joo Yun Lee ◽  
Muhammad Latif ◽  
Haeil Park ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Nitrile Oxide ◽  
Asymmetric Total Synthesis ◽  
Structure Revision

Substrate-Controlled Asymmetric Total Synthesis and Structure Revision of (+)-Itomanallene A

2009 ◽  
Vol 122 (4) ◽  
pp. 764-768 ◽  
Author(s):  
Wonjang Jeong ◽  
Mi Jung Kim ◽  
Hyoungsu Kim ◽  
Sanghee Kim ◽  
Deukjoon Kim ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Asymmetric Total Synthesis ◽  
Structure Revision

Asymmetric Total Synthesis of (+)-Brefeldin A from (S)-Lactate by Triple Chirality Transfer Process and Nitrile Oxide Cycloaddition†,1

2002 ◽  
Vol 67 (3) ◽  
pp. 764-771 ◽  
Author(s):  
Deukjoon Kim ◽  
Jongkook Lee ◽  
Phil Jong Shim ◽  
Joong Inn Lim ◽  
Hyunil Jo ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Transfer Process ◽  
Brefeldin A ◽  
Nitrile Oxide ◽  
Asymmetric Total Synthesis ◽  
Chirality Transfer

ChemInform Abstract: Asymmetric Total Synthesis of (+)-Carneic Acid A and Structure Revision of Its Natural Form.

ChemInform ◽  
2009 ◽  
Vol 40 (52) ◽  
Author(s):  
Shuhei Yamakoshi ◽  
Nobuyuki Hayashi ◽  
Takahiro Suzuki ◽  
Masahisa Nakada
Keyword(s):  
Total Synthesis ◽  
Asymmetric Total Synthesis ◽  
Natural Form ◽  
Structure Revision

scholarly journals Total Synthesis of the Alleged Structure of Crenarchaeol Enables Structure Revision

2020 ◽  
Author(s):  
Mira Holzheimer ◽  
Jaap S. Sinninghe Damsté ◽  
Stefan Schouten ◽  
Adriaan J. Minnaard
Keyword(s):  
Total Synthesis ◽  
Nmr Analysis ◽  
Synthetic Material ◽  
Asymmetric Total Synthesis ◽  
Tetraether Lipid ◽  
Ms Analysis ◽  
Structure Revision ◽  
Membrane Spanning

This study describes the first asymmetric total synthesis of the proposed structure of the archaeal membrane-spanning tetraether lipid crenarchaeol. The synthetic material was compared by NMR and GC-MS analysis with natural crenarchaeol. Detailed NMR analysis ultimately enabled the structure revision of crenarchaeol, identifying one out of 22 sterecenters to be inverted.

Asymmetric total synthesis of (+)-carneic acid A and structure revision of its natural form

2009 ◽  
Vol 50 (38) ◽  
pp. 5372-5375 ◽  
Author(s):  
Shuhei Yamakoshi ◽  
Nobuyuki Hayashi ◽  
Takahiro Suzuki ◽  
Masahisa Nakada
Keyword(s):  
Total Synthesis ◽  
Asymmetric Total Synthesis ◽  
Natural Form ◽  
Structure Revision

Substrate-Controlled Asymmetric Total Synthesis and Structure Revision of (+)-Itomanallene A

2009 ◽  
Vol 49 (4) ◽  
pp. 752-756 ◽  
Author(s):  
Wonjang Jeong ◽  
Mi Jung Kim ◽  
Hyoungsu Kim ◽  
Sanghee Kim ◽  
Deukjoon Kim ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Asymmetric Total Synthesis ◽  
Structure Revision

scholarly journals Total Synthesis of the Alleged Structure of Crenarchaeol Enables Structure Revision

2020 ◽  
Author(s):  
Mira Holzheimer ◽  
Jaap S. Sinninghe Damsté ◽  
Stefan Schouten ◽  
Adriaan J. Minnaard
Keyword(s):  
Total Synthesis ◽  
Nmr Analysis ◽  
Synthetic Material ◽  
Asymmetric Total Synthesis ◽  
Tetraether Lipid ◽  
Ms Analysis ◽  
Structure Revision ◽  
Membrane Spanning

This study describes the first asymmetric total synthesis of the proposed structure of the archaeal membrane-spanning tetraether lipid crenarchaeol. The synthetic material was compared by NMR and GC-MS analysis with natural crenarchaeol. Detailed NMR analysis ultimately enabled the structure revision of crenarchaeol, identifying one out of 22 sterecenters to be inverted.

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