The reversible co-ordination of nitric oxide by the manganese(II) phosphine complexes, MnX2(PR3), in the solid state and in tetrahydrofuran solution

1984 ◽  
pp. 594 ◽  
Author(s):  
David S. Barratt ◽  
Charles A. McAuliffe
Keyword(s):  
Nitric Oxide ◽  
Solid State ◽  
Phosphine Complexes ◽  
Tetrahydrofuran Solution

A solid-state 31P NMR study of 1:1 silver–triphenylphosphine complexes — Interpretation of 1J(107,109Ag,31P) values,

2009 ◽  
Vol 87 (7) ◽  
pp. 1090-1101 ◽  
Author(s):  
Fu Chen ◽  
Se-Woung Oh ◽  
Roderick E. Wasylishen
Keyword(s):  
Solid State ◽  
Spin Coupling ◽  
Coupling Mechanism ◽  
P Values ◽  
X Ray Crystallography ◽  
Phosphine Complexes ◽  
Nmr Study ◽  
Fermi Contact ◽  
Spin Spin Coupling ◽  
Cp Mas Nmr

High-resolution solid-state 31P NMR spectroscopy was used to investigate a series of 1:1 silver–triphenylphosphine complexes, [Ph3PAgX]n, where X is a monovalent anion and n = 1, 2, 3, 4, or ∞. The 31P CP MAS NMR spectra reveal the number of distinct phosphorus sites in these complexes as well as the |1J(109Ag,31P)| values, which range from 401 ± 10 Hz (X = N3–) to 869 ± 10 Hz (X = SO3CF3–). The data obtained here and in earlier investigations indicate that |1J(109Ag,31P)| values for silver–tertiary phosphine complexes decrease as Ag–P bond lengths increase. This experimental conclusion is supported by DFT calculations, which also indicate that the Fermi-contact mechanism is the only important spin–spin coupling mechanism for 1J(109Ag,31P) in these complexes. In addition, the crystal structure of a silver–triphenylphosphine trifluoroacetate tetramer was determined using X-ray crystallography, and the structure of a silver–triphenylphosphine chloride tetramer was reinvestigated.

Solid-State 63Cu, 65Cu, and 31P NMR Spectroscopy of Photoluminescent Copper(I) Triazole Phosphine Complexes

2015 ◽  
Vol 119 (30) ◽  
pp. 8279-8293 ◽  
Author(s):  
Huaguang Yu ◽  
Xiuzhen Tan ◽  
Guy M. Bernard ◽  
Victor V. Terskikh ◽  
Jinglin Chen ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
31P Nmr ◽  
31P Nmr Spectroscopy ◽  
Phosphine Complexes

scholarly journals Novel Solid State Nitric Oxide Sensor Using Siloxane-Poly(Oxypropylene) (PPO)

2013 ◽  
Vol 04 (11) ◽  
pp. 683-688 ◽  
Author(s):  
Rondinelli D. Herculano ◽  
Carlos A. Brunello ◽  
Jair P. Melo Jr. ◽  
Mayler Martins ◽  
Felipe A. Borges ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Solid State ◽  
Nitric Oxide Sensor

A 31P and 199Hg nuclear magnetic resonance and vibrational spectroscopic study of phosphine complexes of Hg(ClO4)2

1984 ◽  
Vol 62 (3) ◽  
pp. 621-627 ◽  
Author(s):  
Tim Allman ◽  
Ram G. Goel
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Magnetic Resonance ◽  
Spectroscopic Study ◽  
Vibrational Spectroscopy ◽  
Low Frequency ◽  
Sample Concentration ◽  
Phosphine Complexes ◽  
Nuclear Magnetic

Cationic complexes of the type [Hg(phosphine)n](ClO4)2 (n = 2, 3, 4) (phosphine = P(t-Bu)3, PCy3, P(4-Me2NC6H4)3, P(4-MeOC6H4)3, P(4-MeC6H4)3, P(3-MeC6H4)3, P(2-MeC6H4)3, P(4-FC6H4)3, P(4-ClC6H4)3) have been prepared and studied by vibrational spectroscopy in the perchlorate and low frequency regions, as well as by 31P and 199Hg nmr. The skeletal Hg—P frequencies have been assigned in both solution and the solid state. It was found that 1J(Hg—P) decreases with increasing phosphine basicity and that it is also dependent upon sample concentration and temperature.

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