Metal–metal bond fission in a trinuclear osmium cluster by triethylphosphine: the X-ray crystal structure of [HOs3(CO)10(PEt3)(CF3CCHCF3)]

A dimeric cyano-rhenium complex with sulphur bridges and a sirect metalmetal bond: preparation and X-ray crystal structure of (Ph4P)4 [Re2(μ2-S)2-(CN)8]4−· 6H20

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)87164-9 ◽

1978 ◽

Vol 26 ◽

pp. L27-L28 ◽

Cited By ~ 6

Author(s):

Michael Laing ◽

Jaean-Marie Bregeault ◽

William P. Griffith

Keyword(s):

Crystal Structure ◽

X Ray ◽

Metal Bond ◽

Rhenium Complex ◽

Metal Metal

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Vibrational spectra of dithioaryl acid complexes of nickel(II), palladium(II), platinum(II), and zinc(II), their sulfur addition products. X-ray crystal structure of the dimer of bis(dithiocumato)platinum(II), a material with a 2.87-Ang. metal-metal bond

Inorganic Chemistry ◽

10.1021/ic50118a026 ◽

1972 ◽

Vol 11 (12) ◽

pp. 3000-3009 ◽

Cited By ~ 32

Author(s):

J. M. Burke ◽

J. P. Fackler

Keyword(s):

Crystal Structure ◽

Vibrational Spectra ◽

X Ray ◽

Metal Bond ◽

Sulfur Addition ◽

Metal Metal

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Facile [1,2] hydrogen-shift reaction promoted by metal–metal bond rupture; X-ray crystal structure of W2(CO)8[C9H14]

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39810001057 ◽

1981 ◽

pp. 1057-1059 ◽

Cited By ~ 12

Author(s):

Jacques Levisalles ◽

Francoise Rose-munch ◽

Henri Rudler ◽

Jean-Claude Daran ◽

Yves Jeannin

Keyword(s):

Crystal Structure ◽

Bond Rupture ◽

X Ray ◽

Hydrogen Shift ◽

Metal Bond ◽

Metal Metal ◽

Shift Reaction

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Is the metal-metal bond length in decacarbonylmanganeserhenium anomalous? X-ray crystal structure determination of MnRe(CO)9L (L = tert-BuNC, P(CH2C6H5)3) and MnRe(CO)8(CNBu-tert) (PPh3)

Inorganic Chemistry ◽

10.1021/ic00049a009 ◽

1992 ◽

Vol 31 (23) ◽

pp. 4756-4761 ◽

Cited By ~ 10

Author(s):

Ann E. Leins ◽

David G. Billing ◽

Demetrius C. Levendis ◽

Johan Du Toit ◽

Neil J. Coville

Keyword(s):

Crystal Structure ◽

Bond Length ◽

Structure Determination ◽

Crystal Structure Determination ◽

X Ray ◽

Metal Bond ◽

Metal Metal

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ChemInform Abstract: A DIMERIC CYANO-RHENIUM COMPLEX WITH SULFUR BRIDGES AND A DIRECT METAL-METAL BOND- PREPARATION AND X-RAY CRYSTAL STRUCTURE OF (PH4P)4(RE2(μ2-S)2(CN)8)4-.6H2O

Chemischer Informationsdienst ◽

10.1002/chin.197816066 ◽

1978 ◽

Vol 9 (16) ◽

Author(s):

M. LAING ◽

J.-M. BREGEAULT ◽

W. P. GRIFFITH

Keyword(s):

Crystal Structure ◽

X Ray ◽

Metal Bond ◽

Rhenium Complex ◽

Metal Metal

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A dimeric platinum(III) system containing a long metal-metal bond. Crystal structure of K4[Pt2(P2O5H2)4CH3I].2H2O

Inorganic Chemistry ◽

10.1021/ic00193a058 ◽

1984 ◽

Vol 23 (25) ◽

pp. 4386-4388 ◽

Cited By ~ 25

Author(s):

Chi Ming Che ◽

Thomas C. W. Mak ◽

Harry B. Gray

Keyword(s):

Crystal Structure ◽

Metal Bond ◽

Metal Metal

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The preparation and crystal structure of µ-oxido-bis[triphenylphosphinenitrosyliridium(I)]: a novel iridium nitrosyl compound containing a bridging oxygen and a bent metal–metal bond

Journal of the Chemical Society D Chemical Communications ◽

10.1039/c2969001374b ◽

1969 ◽

Vol 0 (23) ◽

pp. 1374b-1375 ◽

Cited By ~ 14

Author(s):

P. Carty ◽

A. Walker ◽

M. Mathew ◽

Gus J. Palenik

Keyword(s):

Crystal Structure ◽

Metal Bond ◽

Metal Metal

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ChemInform Abstract: MIXED OXIDATION STATE CONFACIAL BIOCTAHEDRAL COMPLEXES OF TUNGSTEN POSSESSING STRONG METAL-METAL INTERACTION. PART 2. SYNTHESIS, X-RAY CRYSTAL STRUCTURE, AND ELECTRON SPIN RESONANCE STUDIES OF THE W(III)/W(IV) COMPLEX BIS(TETRAPHENYLA

Chemischer Informationsdienst ◽

10.1002/chin.198406252 ◽

1984 ◽

Vol 15 (6) ◽

Author(s):

J. M. BALL ◽

P. M. BOORMAN ◽

K. J. MOYNIHAN ◽

V. D. PATEL ◽

J. F. RICHARDSON ◽

...

Keyword(s):

Crystal Structure ◽

Electron Spin Resonance ◽

Oxidation State ◽

Electron Spin ◽

X Ray ◽

Metal Interaction ◽

Mixed Oxidation ◽

Metal Metal ◽

Spin Resonance

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Metal-metal bond formation and rearrangement of the S2CPR3 ligands in binuclear manganese-molybdenum complexes. X-ray structure of [MnMo(SnPh3)(CO)6(.mu.-S2CPPr-iso3)]

Organometallics ◽

10.1021/om00032a007 ◽

1993 ◽

Vol 12 (8) ◽

pp. 2888-2890 ◽

Cited By ~ 14

Author(s):

Daniel Miguel ◽

Julio A. Perez-Martinez ◽

Victor Riera ◽

Santiago Garcia-Granda

Keyword(s):

Bond Formation ◽

Molybdenum Complexes ◽

X Ray ◽

Metal Bond ◽

Metal Metal

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Tetraphenylphosphonium-nonachlorodivanadat(III), (PPh4)3[V2Cl9] · 7 CH2Cl2 / Tetraphenylphosphonium Nonachlorodivanadate(III), (PPh4)3[V2Cl9] · 7 CH2Cl2

Zeitschrift für Naturforschung B ◽

10.1515/znb-1992-0609 ◽

1992 ◽

Vol 47 (6) ◽

pp. 814-818 ◽

Cited By ~ 2

Author(s):

Karin Ruhlandt-Senge ◽

Alfred Dirk Bacher ◽

Gertraude Koellner ◽

Birgit Siewert ◽

Ulrich Müller

Keyword(s):

Crystal Structure ◽

Structure Analysis ◽

Crystal Structure Analysis ◽

Crystal Data ◽

X Ray ◽

Metal Bonding ◽

Metal Metal ◽

Tetragonal Pyramidal ◽

Approximate Composition ◽

Insoluble Product

Reaction of VC14 with (Me3Si)2S in CH2C12 yields an insoluble product with the approximate composition VSC12. Its reaction with PPh4Cl in CH2Cl2 affords (PPh4)3[V2Cl9] · 7 CH2Cl2, whereas PPh4[VOCl4] is formed in the presence of oxygen. According to an X-ray crystal structure analysis, (PPh4)3[V2Cl9] · 7 CH2Cl2 contains [V2C19]3- ions having two face-sharing coordination octahedra but no significant metal-metal bonding (V-V distance 327.5 pm). Crystal data: a = 1386.4(7), b = 1405.6(7), c = 2710(2) pm, α = 95.800(5), β = 95.370(5), γ = 118.11(3)°, triclinic, Ρ 1̄, Ζ = 2; R = 0.066 for 8779 observed reflexions. PPh4[VOCl4] is isotypic with AsPh4[VOCl4] and contains tetragonal-pyramidal [VOCl4]- ions; tetragonal, P4/n, Z = 2, a = 1264.5(2), c = 772.0(2) pm; R = 0.050 for 654 observed reflexions.

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