Vibrational spectra of dithioaryl acid complexes of nickel(II), palladium(II), platinum(II), and zinc(II), their sulfur addition products. X-ray crystal structure of the dimer of bis(dithiocumato)platinum(II), a material with a 2.87-Ang. metal-metal bond

1972 ◽  
Vol 11 (12) ◽  
pp. 3000-3009 ◽  
Author(s):  
J. M. Burke ◽  
J. P. Fackler
Keyword(s):  
Crystal Structure ◽  
Vibrational Spectra ◽  
X Ray ◽  
Metal Bond ◽  
Sulfur Addition ◽  
Metal Metal

Facile [1,2] hydrogen-shift reaction promoted by metal–metal bond rupture; X-ray crystal structure of W2(CO)8[C9H14]

1981 ◽  
pp. 1057-1059 ◽  
Author(s):  
Jacques Levisalles ◽  
Francoise Rose-munch ◽  
Henri Rudler ◽  
Jean-Claude Daran ◽  
Yves Jeannin
Keyword(s):  
Crystal Structure ◽  
Bond Rupture ◽  
X Ray ◽  
Hydrogen Shift ◽  
Metal Bond ◽  
Metal Metal ◽  
Shift Reaction

Calcium Carbodiimide Compounds Revisited – Syntheses, Single Crystal Structure Determination and Vibrational Spectra of Ca11N6[CN2]2, Ca4N2[CN2] and Ca[CN2]

2008 ◽  
Vol 63 (5) ◽  
pp. 530-536 ◽  
Author(s):  
Olaf Reckeweg ◽  
Francis J. DiSalvo
Keyword(s):  
Crystal Structure ◽  
Raman Spectrum ◽  
Single Crystal ◽  
Single Crystals ◽  
Vibrational Spectra ◽  
Structure Determination ◽  
X Ray ◽  
Characteristic Features ◽  
Reported Data ◽  
Correct Data

Single crystals of Ca11N6[CN2]2 (dark red needles, tetragonal, P42/mnm (no. 136), a = 1456.22(5), and c = 361.86(2) pm, Z = 2), Ca4N2[CN2] (transparent yellow needles, orthorhombic, Pnma (no. 62), a = 1146.51(11), b = 358.33(4), and c = 1385.77(13) pm, Z = 4) and Ca[CN2] (transparent, colorless, triangular plates, rhombohedral, R3̅m (no. 166), a = 369.00(3), and c = 1477.5(3) pm, Z = 3) were obtained by the reaction of Na2[CN2], CaCl2 and Ca3N2 (if demanded by stoichiometry) in arc-welded Ta ampoules at temperatures between 1200 - 1400 K. Their crystal structures were re-determined by means of single crystal X-ray structure analyses. Additionally, the Raman spectra were recorded on these same single crystals, whereas the IR spectra were obtained with the KBr pellet technique. The title compounds exhibit characteristic features for carbodiimide units with D∞h symmetry (d(C-N) = 121.7 - 123.8 pm and ∡ (N-C-N) = 180°). The vibrational frequencies of these units are in the expected range (Ca11N6[CN2]2: νs = 1230, νs = 2008; δ = 673/645/624 cm−1; Ca4N2[CN2]: νs = 1230, νs = 1986; δ = 672/647 cm−1; Ca[CN2]: νs = 1274, νs = 2031, δ = 668 cm−1). The structural results are more precise than the previously reported data, and with the newly attained Raman spectrum of Ca11N6[CN2]2 we correct data reported earlier.

A dimeric platinum(III) system containing a long metal-metal bond. Crystal structure of K4[Pt2(P2O5H2)4CH3I].2H2O

1984 ◽  
Vol 23 (25) ◽  
pp. 4386-4388 ◽  
Author(s):  
Chi Ming Che ◽  
Thomas C. W. Mak ◽  
Harry B. Gray
Keyword(s):  
Crystal Structure ◽  
Metal Bond ◽  
Metal Metal

ChemInform Abstract: SYNTHESES, X-RAY CRYSTAL STRUCTURE, AND VIBRATIONAL SPECTRA OF L-CYSTEINATO(METHYL)MERCURY(II) MONOHYDRATE

1975 ◽  
Vol 6 (20) ◽  
pp. no-no
Author(s):  
NICHOLAS J. TAYLOR ◽  
YAU S. WONG ◽  
PETER C. CHIEH ◽  
ARTHUR J. CARTY
Keyword(s):  
Crystal Structure ◽  
Vibrational Spectra ◽  
Methyl Mercury ◽  
X Ray
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