Chlorine isotope effects in dehydrochlorination. A mechanistic crossover at the E1cB-E2 borderline induced by a change in para-substituent

1976 ◽  
pp. 775b ◽  
Author(s):  
Alan Grout ◽  
Duncan J. McLennan ◽  
Irving H. Spackman
Keyword(s):  
Isotope Effects ◽  
Chlorine Isotope

Carbon and Chlorine Isotope Effects During Abiotic Reductive Dechlorination of Polychlorinated Ethanes

2007 ◽  
Vol 41 (13) ◽  
pp. 4662-4668 ◽  
Author(s):  
Thomas B. Hofstetter ◽  
Christopher M. Reddy ◽  
Linnea J. Heraty ◽  
Michael Berg ◽  
Neil C. Sturchio
Keyword(s):  
Reductive Dechlorination ◽  
Isotope Effects ◽  
Chlorine Isotope

scholarly journals Mechanistic Dichotomy in Bacterial Trichloroethene Dechlorination Revealed by Carbon and Chlorine Isotope Effects

2019 ◽  
Vol 53 (8) ◽  
pp. 4245-4254 ◽  
Author(s):  
Christina Lihl ◽  
Lisa M. Douglas ◽  
Steffi Franke ◽  
Alfredo Pérez-de-Mora ◽  
Armin H. Meyer ◽  
...  
Keyword(s):  
Isotope Effects ◽  
Chlorine Isotope

Chlorine isotope effects in the solvolysis of substituted 1-phenylethyl chlorides

1986 ◽  
Vol 64 (6) ◽  
pp. 1201-1205 ◽  
Author(s):  
Duncan J. McLennan ◽  
Allan R. Stein ◽  
Brian Dobson
Keyword(s):  
Transition State ◽  
Theoretical Calculations ◽  
Isotope Effects ◽  
Chloride Ion ◽  
Solvent Composition ◽  
Solvent Mixtures ◽  
Chlorine Isotope ◽  
Water Solvent ◽  
Alcohol Water ◽  
Substituted 1

Kinetic chlorine isotope effects attending the solvolysis of several ring-substituted 1-phenylethyl chlorides in alcohol–water solvent mixtures are reported. The k35/k37 values are insensitive to the identity of ring substituents and to solvent composition. Results are interpreted in terms of an SN1 heterolytic process incorporating a significant amount of internal return. Theoretical calculations suggest that the incipient chloride ion in the transition state may be strongly hydrogen-bonded.

Sign in / Sign up

Export Citation Format

Share Document