Amine-functionalized nanoporous thin films from a poly(ethylene oxide)-block-polystyrene diblock copolymer bearing a photocleavable o-nitrobenzyl carbamate junction

Soft Matter ◽  
2012 ◽  
Vol 8 (16) ◽  
pp. 4486 ◽  
Author(s):  
Cé Guinto Gamys ◽  
Jean-Marc Schumers ◽  
Alexandru Vlad ◽  
Charles-André Fustin ◽  
Jean-François Gohy
Keyword(s):  
Thin Films ◽  
Ethylene Oxide ◽  
Diblock Copolymer ◽  
Amine Functionalized ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

Revealing the growth of copper on polystyrene-block-poly(ethylene oxide) diblock copolymer thin films with in situ GISAXS

Nanoscale ◽  
2021 ◽  
Author(s):  
Simon Jakob Schaper ◽  
Franziska C. Löhrer ◽  
Senlin Xia ◽  
Christina Geiger ◽  
Matthias Schwartzkopf ◽  
...  
Keyword(s):  
Thin Films ◽  
Ethylene Oxide ◽  
Polymer Electrolyte ◽  
Diblock Copolymer ◽  
Active Material ◽  
Ionic Conductor ◽  
Electrical Conductor ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

Copper (Cu) as excellent electrical conductor and the amphiphilic diblock copolymer polystyrene-block-poly(ethylene oxide) (PS b PEO) as polymer electrolyte and ionic conductor can be combined with an active material in...

Molecular Dynamics Study of Polystyrene-b-poly(ethylene oxide) Asymmetric Diblock Copolymer Systems

Langmuir ◽  
2017 ◽  
Vol 33 (36) ◽  
pp. 8856-8868 ◽  
Author(s):  
M. Dobies ◽  
M. Makrocka-Rydzyk ◽  
J. Jenczyk ◽  
M. Jarek ◽  
R. J. Spontak ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Ethylene Oxide ◽  
Diblock Copolymer ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

scholarly journals Effect of Environmental Humidity on the Ionic Transport of Poly(ethylene Oxide) Thin Films by Local Dielectric Spectroscopy

2019 ◽  
Author(s):  
Paul Markus ◽  
Daniel E Martínez-Tong ◽  
Georg Papastavrou ◽  
Angel Alegria
Keyword(s):  
Thin Films ◽  
Ethylene Oxide ◽  
Amorphous Phase ◽  
Dielectric Spectroscopy ◽  
Ionic Transport ◽  
Oxide Thin Films ◽  
Environmental Humidity ◽  
Dielectric Contrast ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

<div><div><div><p>The effect of humidity on the ionic transport in the amorphous phase of poly(ethylene oxide) thin films has been studied by via local dielectric spectroscopy. We explored a controlled humidity range between 15 %RH and 50 %RH. AFM-based local dielectric imaging allowed to obtain simultaneously the thin films topography and the corresponding dielectric contrast maps. No humidity effect on the film topography was observed whereas large variation of the dielectric signal could be detected. In addition, we observed a clear dielectric contrast in different locations on the thin film surface. At selected regions with high contrast in the dielectric maps, we performed nanoDielectric Spectroscopy (nDS) measurements covering the frequency range from 10 Hz to 100 kHz. By modeling these spectroscopy results, we quantified the conductivity of the amorphous phase of the semicrystalline poly(ethylene oxide) films. The crystalline fraction of the PEO thin films was extracted and found to be about 36%, independently of humidity. However, the average conductivity increased drastically from 2×10-10 to 5×10-9 S/cm, by changing environmental humidity in the explore %RH range.</p></div></div></div>

Systematic Control of Self-Seeding Crystallization Patterns of Poly(ethylene oxide) in Thin Films

2018 ◽  
Vol 51 (5) ◽  
pp. 1626-1635 ◽  
Author(s):  
Binghua Wang ◽  
Shaohua Tang ◽  
Yan Wang ◽  
Changyu Shen ◽  
Renate Reiter ◽  
...  
Keyword(s):  
Thin Films ◽  
Ethylene Oxide ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Systematic Control

scholarly journals Synthesis and self-assembly of a novel amphiphilic diblock copolymer consisting of isotactic polystyrene and 1,4-trans-polybutadiene-graft-poly(ethylene oxide)

RSC Advances ◽  
2018 ◽  
Vol 8 (23) ◽  
pp. 12752-12759
Author(s):  
HuaQing Liang ◽  
QiHua Zhou ◽  
YongJiang Long ◽  
WanChu Wei ◽  
Shuo Feng ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Amphiphilic Diblock Copolymer ◽  
Isotactic Polystyrene ◽  
Poly Ethylene Oxide ◽  
Assembly Behavior ◽  
Poly Ethylene

Herein, a novel amphiphilic diblock copolymer consisting of isotactic polystyrene and 1,4-trans-polybutadiene-graft-poly(ethylene oxide) was synthesized and its self-assembly behavior was investigated.

scholarly journals Effect of environmental humidity on the ionic transport of poly(ethylene oxide) thin films, investigated by local dielectric spectroscopy

Soft Matter ◽  
2020 ◽  
Vol 16 (13) ◽  
pp. 3203-3208 ◽  
Author(s):  
Paul Markus ◽  
Daniel E. Martínez-Tong ◽  
Georg Papastavrou ◽  
Angel Alegria
Keyword(s):  
Thin Films ◽  
Relative Humidity ◽  
Ethylene Oxide ◽  
Dielectric Spectroscopy ◽  
Ionic Transport ◽  
Oxide Thin Films ◽  
Environmental Humidity ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

The laterally-resolved conductivity of PEO thin films increases with relative humidity, as determined by local dielectric spectroscopy: an AFM-based electrical technique.

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