Effect of Zr substitution for Ce in BaCe0.8Gd0.15Pr0.05O3−δ on the chemical stability in CO2 and water, and electrical conductivity

RSC Advances ◽  
2013 ◽  
Vol 3 (11) ◽  
pp. 3599 ◽  
Author(s):  
Sukhdeep Gill ◽  
Ramaiyan Kannan ◽  
Nicola Maffei ◽  
Venkataraman Thangadurai
Keyword(s):  
Electrical Conductivity ◽  
Chemical Stability

scholarly journals Solvothermal Preparation of Spherical Bi2O3 Nanoparticles Uniformly Distributed on Ti3C2Tx for Enhanced Capacitive Performance

2021 ◽  
Author(s):  
Tao Li ◽  
Xuefeng Chang ◽  
Lifang Mei ◽  
Xiayun Shu ◽  
Jidong Ma ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Chemical Stability ◽  
Layered Structure ◽  
Layered Material ◽  
Two Dimensional ◽  
Capacitive Performance ◽  
Solvothermal Preparation

Ti3C2Tx is a promising new two-dimensional layered material for supercapacitors with good electrical conductivity and chemical stability. However, Ti3C2Tx has problems such as collapse of the layered structure and low...

Influence of Sintering Additive on the Electrical Conductivity, Chemical Stability and Sinterability of BaCe0.55Zr0.3Y0.15O3- 

2015 ◽  
Vol 68 (1) ◽  
pp. 467-471
Author(s):  
H. An ◽  
D. Shin ◽  
S.-M. Choi ◽  
J. Hong ◽  
K. J. Yoon ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Chemical Stability ◽  
Sintering Additive

Synthesis, Electrical Properties and Chemical Stability of BaCe0.7In0.3-xGdxO3-δ

2016 ◽  
Vol 848 ◽  
pp. 401-410 ◽  
Author(s):  
Jia Huan Xu ◽  
Wei Han ◽  
Hui Ding ◽  
Wei Jin Chen ◽  
Jun Xiang
Keyword(s):  
Electrical Conductivity ◽  
Electrical Properties ◽  
Chemical Stability ◽  
Perovskite Structure ◽  
Doping Concentration ◽  
Interplanar Spacing ◽  
Sol Gel ◽  
Impedance Spectra ◽  
Spectra Analysis ◽  
Diffraction Angle

In3+, Gd3+ were selected as substitution elements for Ce4+ in order to increase electrical conductivity and chemical stability of BaCeO3. A modified sol-gel method was used to fabricate BaCe0.7In0.3-xGdxO3-δ (x = 0, 0.1, 0.2, 0.3) nanopowders. XRD results indicated that the diffraction angle moved to lower with increase of the Gd3 + doping concentration, so that the interplanar spacing gradually increased. The impedance spectra analysis showed that conductivity first increased (x = 0~0.2) and then decreased with the Gd3 + doping increase. The total conductivities at 800oC were 3.8 × 10-3 S·cm-1 (x = 0), 8.0 × 10-3 S· cm-1 (x = 0.1), 2.5 × 10-2 S· cm-1 (x = 0.2), 1.36 × 10-2 S ·cm-1 (x = 0.3). Chemical stability test in CO2 show that all samples except for x=0.3 sample calcination at 800oC for 2h under 100% CO2 and x=0, 0.1 samples heating in boiling water for 12h kept main perovskite structure. Therefore, x=0.1 sample show better electrical conductivity and chemical stability.

Chemical stability and electrical conductivity of BaCe0.4Zr0.4Gd0.1Dy0.1O3−δ perovskite

2015 ◽  
Vol 41 (9) ◽  
pp. 10856-10860 ◽  
Author(s):  
Yen-Chang Tsai ◽  
San-Yuan Chen ◽  
Jeng-Han Wang ◽  
Pu-Wei Wu ◽  
Po-Chun Chen
Keyword(s):  
Electrical Conductivity ◽  
Chemical Stability

scholarly journals Electrical conductivity and chemical stability of BaCe0·8 − x A x Gd0·2O3 − δ (A = In, Zr, Ta; x = 0, 0·1) ceramics

2013 ◽  
Vol 36 (3) ◽  
pp. 395-401 ◽  
Author(s):  
XIAO-MING LIU ◽  
YI-JING GU ◽  
ZHAN-GUO LIU ◽  
JIA-HU OUYANG ◽  
FU-YAO YAN YAN ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Chemical Stability
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