scholarly journals Effect of A-Site Cation Ordering on Chemical Stability, Oxygen Stoichiometry and Electrical Conductivity in Layered LaBaCo2O5+δ Double Perovskite

Materials ◽  
2016 ◽  
Vol 9 (3) ◽  
pp. 154 ◽  
Author(s):  
Carlos Bernuy-Lopez ◽  
Kristin Høydalsvik ◽  
Mari-Ann Einarsrud ◽  
Tor Grande
2020 ◽  
Vol 4 (5) ◽  
pp. 1519-1529 ◽  
Author(s):  
Hayato Togano ◽  
Kaisei Asai ◽  
Seiji Oda ◽  
Hidekazu Ikeno ◽  
Shogo Kawaguchi ◽  
...  

Oxygen-deficient double perovskite oxides PrBaCo2O6−δ exhibit highly active hydrogen evolution reaction catalysis, which is associated with multiple factors: oxygen deficiency, high Co valence, and A-site cation ordering.


Materials ◽  
2018 ◽  
Vol 11 (2) ◽  
pp. 196 ◽  
Author(s):  
Carlos Bernuy-Lopez ◽  
Laura Rioja-Monllor ◽  
Takashi Nakamura ◽  
Sandrine Ricote ◽  
Ryan O’Hayre ◽  
...  

2017 ◽  
Vol 5 (25) ◽  
pp. 13019-13031 ◽  
Author(s):  
Nam-In Kim ◽  
Rana Arslan Afzal ◽  
Sung Ryul Choi ◽  
Sung Won Lee ◽  
Docheon Ahn ◽  
...  

A-site cation doping in perovskite-based materials (ABO3 formula) has a significant effect on the bifunctional oxygen activity of the electrocatalysts with chemical stability, enabling the design of highly active, durable, and cost-effective catalysts.


2021 ◽  
Author(s):  
Tao Li ◽  
Xuefeng Chang ◽  
Lifang Mei ◽  
Xiayun Shu ◽  
Jidong Ma ◽  
...  

Ti3C2Tx is a promising new two-dimensional layered material for supercapacitors with good electrical conductivity and chemical stability. However, Ti3C2Tx has problems such as collapse of the layered structure and low...


2015 ◽  
Vol 68 (1) ◽  
pp. 467-471
Author(s):  
H. An ◽  
D. Shin ◽  
S.-M. Choi ◽  
J. Hong ◽  
K. J. Yoon ◽  
...  

2015 ◽  
Vol 182 ◽  
pp. 227-239 ◽  
Author(s):  
Tae Ho Shin ◽  
Jae-Ha Myung ◽  
Maarten Verbraeken ◽  
Guntae Kim ◽  
John T. S. Irvine

A-site ordered PrBaMn2O5+δ was investigated as a potential cathode for CO2 electrolysis using a La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) electrolyte. The A-site ordered layered double perovskite, PrBaMn2O5+δ, was found to enhance electrocatalytic activity for CO2 reduction on the cathode side since it supports mixed valent transition metal cations such as Mn, which could provide high electrical conductivity and maintain a large oxygen vacancy content, contributing to fast oxygen ion diffusion. It was found that during the oxidation of the reduced PrBaMn2O5+δ (O5 phase) to PrBaMn2O6−δ (O6 phase), a reversible oxygen switchover in the lattice takes place. In addition, here the successful CO2 electrolysis was measured in LSGM electrolyte with this novel oxide electrode. It was found that this PrBaMn2O5+δ, layered perovskite cathode exhibits a performance with a current density of 0.85 A cm−2 at 1.5 V and 850 °C and the electrochemical properties were also evaluated by impedance spectroscopy.


2018 ◽  
Vol 466 ◽  
pp. 133-137 ◽  
Author(s):  
Yanchun Hu ◽  
Tengyu Guo ◽  
Xianwei Wang ◽  
Yawen Cui ◽  
Weixia Li ◽  
...  

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