Excellent catalytic performance of graphite oxide in the selective oxidation of glutaraldehyde by aqueous hydrogen peroxide

RSC Advances ◽  
2012 ◽  
Vol 2 (18) ◽  
pp. 7135 ◽  
Author(s):  
Xiaofeng Chu ◽  
Quanjing Zhu ◽  
Wei-Lin Dai ◽  
Kangnian Fan
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Graphite Oxide ◽  
Catalytic Performance ◽  
Aqueous Hydrogen Peroxide ◽  
Excellent Catalytic Performance

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

A novel Cu-nanowire@Quasi-MOF via mild pyrolysis of a bimetal-MOF for the selective oxidation of benzyl alcohol in air

2019 ◽  
Vol 3 (11) ◽  
pp. 2363-2373 ◽  
Author(s):  
Yan Shen ◽  
Li-Wei Bao ◽  
Fang-Zhou Sun ◽  
Tong-Liang Hu
Keyword(s):  
Thermal Decomposition ◽  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
Catalytic Performance ◽  
Oxidation Of Benzyl Alcohol ◽  
Mild Pyrolysis ◽  
First Time ◽  
Excellent Catalytic Performance

A Cu-nanowire@Quasi-MOF was synthesized using a Cu/Co bimetal-MOF via a thermal decomposition strategy for the first time. The Cu-nanowire@Quasi-MOF exhibits excellent catalytic performance in the selective oxidation of benzyl alcohol in air.

scholarly journals Magnetic N-containing carbon spheres derived from sustainable chitin for the selective oxidation of C–H bonds

RSC Advances ◽  
2017 ◽  
Vol 7 (82) ◽  
pp. 51831-51837 ◽  
Author(s):  
Yunrui Zhang ◽  
Haihong Niu ◽  
Xiangjie Zhang ◽  
Junxiu Pan ◽  
Yang Dong ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Carbon Material ◽  
Raw Materials ◽  
Catalytic Performance ◽  
Iron Nitrate ◽  
Carbon Spheres ◽  
Excellent Catalytic Performance

Magnetic N-containing carbon spheres were synthesized using sustainable N-acetyl-d-glucosamine (NAG) and iron nitrate as raw materials. This carbon material exhibited excellent catalytic performance in the C–H bond oxidation.

Insights into the direct selective oxidation of methane to methanol over ZSM-5 zeolytes in aqueous hydrogen peroxide

2020 ◽  
Vol 353 ◽  
pp. 269-278 ◽  
Author(s):  
Saeed Al-Shihri ◽  
Christian J. Richard ◽  
Hamid Al-Megren ◽  
David Chadwick
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Aqueous Hydrogen Peroxide ◽  
Oxidation Of Methane

scholarly journals Fast Degradation of Bisphenol A in Water by Nanostructured CuNPs@CALB Biohybrid Catalysts

Nanomaterials ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 7 ◽  
Author(s):  
Noelia Losada-Garcia ◽  
Alba Rodriguez-Otero ◽  
Jose M. Palomo
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Bisphenol A ◽  
Copper Nanoparticles ◽  
Room Temperature ◽  
Catalytic Performance ◽  
Cu2o Nanoparticles ◽  
Nanoparticle Sizes ◽  
Excellent Catalytic Performance ◽  
Excellent Stability

Copper nanoparticles–enzyme biohybrid is a promising material for the remediation of contaminated waters, but its function is influenced by its effect on degradation organic pollutants. This study is the first investigation into the fast degradation of a high amount of Bisphenol A (BPA) in water at neutral pH and room temperature. Four different CuNPs biohybrids with different cu species and nanoparticle sizes were used as catalysts. The biohybrid CuNPs@CALB-3, which contained Cu2O nanoparticles of around 10 nm size, showed excellent catalytic performance removing >95% BPA content (45 ppm) in an aqueous solution in 20 min in the presence of hydrogen peroxide at pH 8 using 1.5 g/L of a catalyst. The catalyst showed excellent stability and recyclability at these conditions.

Composites of [γ-H2PV2W10O40]3− and [α-SiW12O40]4− supported on Fe2O3 as heterogeneous catalysts for selective oxidation with aqueous hydrogen peroxide

2015 ◽  
Vol 5 (5) ◽  
pp. 2602-2611 ◽  
Author(s):  
Ye Wang ◽  
Keigo Kamata ◽  
Ryo Ishimoto ◽  
Yoshiyuki Ogasawara ◽  
Kosuke Suzuki ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
High Performance ◽  
Heterogeneous Catalysts ◽  
Aqueous Hydrogen Peroxide

The titled heterogeneous catalysts showed high performance for selective oxidation with H2O2.

scholarly journals Effect of Ce doping on the structure–activity relationship of MoVOx composite metal oxides

RSC Advances ◽  
2021 ◽  
Vol 11 (57) ◽  
pp. 36007-36015
Author(s):  
Luyao Deng ◽  
Shuangming Li ◽  
Yongwei Liu ◽  
Zixuan Lu ◽  
Yaoxin Fan ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
Catalytic Performance ◽  
Structure Activity Relationship ◽  
Activity Relationship ◽  
Structure Activity ◽  
Oxidation Of Benzyl Alcohol ◽  
Relationship Of ◽  
Excellent Catalytic Performance

Ce-doped MoVOx with disperse rod-shaped exhibits excellent catalytic performance in selective oxidation of benzyl alcohol.

scholarly journals Inside Cover: Selective Oxidation with Aqueous Hydrogen Peroxide by [PO4{WO(O2)2}4]3−Supported on Zinc-Modified Tin Dioxide (ChemCatChem 7/2015)

ChemCatChem ◽  
2015 ◽  
Vol 7 (7) ◽  
pp. 1032-1032
Author(s):  
Susumu Nojima ◽  
Keigo Kamata ◽  
Kosuke Suzuki ◽  
Kazuya Yamaguchi ◽  
Noritaka Mizuno
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Tin Dioxide ◽  
Aqueous Hydrogen Peroxide
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