Copolymers featuring pentafluorophenyl ester and photolabile amine units: synthesis and application as reactive photopatterns

2013 ◽  
Vol 4 (4) ◽  
pp. 891 ◽  
Author(s):  
Hui Zhao ◽  
Patrick Theato
Keyword(s):  
Pentafluorophenyl Ester

Irreversible Inhibition of Metallo-β-lactamase (IMP-1) by 3-(3-Mercaptopropionylsulfanyl)propionic Acid Pentafluorophenyl Ester

2005 ◽  
Vol 117 (25) ◽  
pp. 3929-3932 ◽  
Author(s):  
Hiromasa Kurosaki ◽  
Yoshihiro Yamaguchi ◽  
Toshihiro Higashi ◽  
Kimitaka Soga ◽  
Satoshi Matsueda ◽  
...  
Keyword(s):  
Propionic Acid ◽  
Irreversible Inhibition ◽  
Pentafluorophenyl Ester

scholarly journals Dependency of the regio- and stereoselectivity of intramolecular, ring-closing glycosylations upon the ring size

2011 ◽  
Vol 7 ◽  
pp. 1609-1619 ◽  
Author(s):  
Patrick Claude ◽  
Christian Lehmann ◽  
Thomas Ziegler
Keyword(s):  
Molecular Modeling ◽  
Protecting Groups ◽  
Ring Size ◽  
Stacking Interaction ◽  
Aromatic Stacking ◽  
Pentafluorophenyl Ester ◽  
Intramolecular Ring

Phenyl 3,4,6-tri-O-benzyl-2-O-(3-carboxypropionyl)-1-thio-β-D-galactopyranoside (1) was condensed via its pentafluorophenyl ester 2 with 5-aminopentyl (4a), 4-aminobutyl (4b), 3-aminopropyl (4c) and 2-aminoethyl 4,6-O-benzylidene-β-D-glucopyranoside (4d), prepared from the corresponding N-Cbz protected glucosides 3a–d, to give the corresponding 2-[3-(alkylcarbamoyl)propionyl] tethered saccharides 5a–d. Intramolecular, ring closing glycosylation of the saccharides with NIS and TMSOTf afforded the tethered β(1→3) linked disaccharides 6a–c, the α(1→3) linked disaccharides 7a–d and the α(1→2) linked disaccharide 8d in ratios depending upon the ring size formed during glycosylation. No β(1→2) linked disaccharides were formed. Molecular modeling of saccharides 6–8 revealed that a strong aromatic stacking interaction between the aromatic parts of the benzyl and benzylidene protecting groups in the galactosyl and glucosyl moieties was mainly responsible for the observed regioselectivity and anomeric selectivity of the ring-closing glycosylation step.

Pentafluorophenyl Ester-Functionalized Phosphorylcholine Polymers: Preparation of Linear, Two-Arm, and Grafted Polymer–Protein Conjugates

2012 ◽  
Vol 13 (7) ◽  
pp. 2099-2109 ◽  
Author(s):  
Samantha McRae ◽  
Xiangji Chen ◽  
Katrina Kratz ◽  
Debasis Samanta ◽  
Elizabeth Henchey ◽  
...  
Keyword(s):  
Grafted Polymer ◽  
Protein Conjugates ◽  
Pentafluorophenyl Ester
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