DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones

2013 ◽  
Vol 37 (6) ◽  
pp. 1684-1687 ◽  
Author(s):  
Weizhou Huang ◽  
Chuanfa Ni ◽  
Yanchuan Zhao ◽  
Jinbo Hu
Keyword(s):  
Tertiary Amines ◽  
Metal Free ◽  
Dehydrogenative Coupling

ChemInform Abstract: DIAD-Mediated Metal-Free Cross Dehydrogenative Coupling Between Tertiary Amines and α-Fluorinated Sulfones.

ChemInform ◽  
2013 ◽  
Vol 44 (44) ◽  
pp. no-no
Author(s):  
Weizhou Huang ◽  
Chuanfa Ni ◽  
Yanchuan Zhao ◽  
Jinbo Hu
Keyword(s):  
Tertiary Amines ◽  
Metal Free ◽  
Dehydrogenative Coupling

ChemInform Abstract: Metal-Free Visible-Light Induced Cross-Dehydrogenative Coupling of Tertiary Amines with Diazo Compounds.

ChemInform ◽  
2015 ◽  
Vol 46 (7) ◽  
pp. no-no
Author(s):  
Tiebo Xiao ◽  
Linyong Li ◽  
Guoliang Lin ◽  
Zong-wan Mao ◽  
Lei Zhou
Keyword(s):  
Visible Light ◽  
Diazo Compounds ◽  
Tertiary Amines ◽  
Metal Free ◽  
Dehydrogenative Coupling

Metal-Free Visible-Light Induced Cross-Dehydrogenative Coupling of Tertiary Amines with Diazo Compounds

2014 ◽  
Vol 16 (16) ◽  
pp. 4232-4235 ◽  
Author(s):  
Tiebo Xiao ◽  
Linyong Li ◽  
Guoliang Lin ◽  
Zong-wan Mao ◽  
Lei Zhou
Keyword(s):  
Visible Light ◽  
Diazo Compounds ◽  
Tertiary Amines ◽  
Metal Free ◽  
Dehydrogenative Coupling

Metal-Free Synthesis of α-Aminophosphonates from Tertiary Amines and P(O)H Compounds via a Cross-Dehydrogenative Coupling Reaction

Synlett ◽  
2018 ◽  
Vol 29 (20) ◽  
pp. 2697-2700 ◽  
Author(s):  
Guo Tang ◽  
Binzhou Lin ◽  
Guozhang Lu ◽  
Rongcan Lin ◽  
Yiqun Cui ◽  
...  
Keyword(s):  
Tertiary Amine ◽  
Coupling Reaction ◽  
Transition Metal Catalysts ◽  
Tertiary Amines ◽  
Butyl Hydroperoxide ◽  
Metal Free ◽  
Tert Butyl ◽  
Dehydrogenative Coupling ◽  
Tert Butyl Hydroperoxide ◽  
Aromatic And Aliphatic Amines

The various α-aminophosphonates have been prepared from tertiary aromatic and aliphatic amines with P(O)H compounds via a tert-butyl hydroperoxide mediated cross-dehydrogenative coupling reaction, eliminating the need for transition-metal catalysts. The oxidation of tertiary amine by tert-butyl hydroperoxide generates an iminium cation intermediate. A further addition of P(O)H compound to iminium cation gives the desired product.

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