ALD/MLD of novel layer-engineered Zn-based inorganic–organic hybrid thin films using heterobifunctional 4-aminophenol as an organic precursor

2013 ◽  
Vol 42 (11) ◽  
pp. 3869 ◽  
Author(s):  
Anjali Sood ◽  
Pia Sundberg ◽  
Maarit Karppinen
2007 ◽  
Vol 270 (2) ◽  
pp. 414-418 ◽  
Author(s):  
Yuanjing Cui ◽  
Guodong Qian ◽  
Lujian Chen ◽  
Junkuo Gao ◽  
Minquan Wang

2015 ◽  
Vol 44 (44) ◽  
pp. 19194-19199 ◽  
Author(s):  
A. Tanskanen ◽  
M. Karppinen

Here we present novel layer-by-layer deposition processes for the fabrication of inorganic–organic hybrid thin films of the (–Fe–O–C6H4–O–)n type and also superlattices where N thicker iron oxide layer blocks alternate with monomolecular-thin organic layers.


2016 ◽  
Vol 45 (26) ◽  
pp. 10730-10735 ◽  
Author(s):  
E. Ahvenniemi ◽  
M. Karppinen

New types of transition metal–organic hybrid thin films are fabricated with the emerging atomic/molecular layer deposition (ALD/MLD) technique through sequential gas-surface reactions from Mn(thd)3, Co(thd)2, Co(acac)3 and terephthalic acid (1,4-benzenedicarboxylic acid) precursors.


2010 ◽  
Vol 17 (03) ◽  
pp. 277-281 ◽  
Author(s):  
HOYYUL PARK ◽  
MYEONGSANG AHN ◽  
MOONKYONG NA

We investigated the properties of inorganic–organic hybrid thin films prepared by sol–gel reaction. Sol solutions were synthesized by using two kinds of nanosized boehmite and methyltrimethoxysilane (MTMS) in variation with the amount of MTMS at different reaction times. Boehmite nano sol of spherical and fibrous shapes was used as inorganic material, and MTMS was used as organic material. The morphology of boehmite nano sol powder was observed by transmission electron microscopy. Coating sols were prepared from boehmite sol and MTMS by sol–gel reaction. Physical and chemical properties of thin films prepared from boehmite and MTMS sols were investigated. Surface hydrophobicity, roughness, thickness, thermal resistance and electrical resistivity of boehmite/MTMS thin films were investigated.


2009 ◽  
Vol 19 (1) ◽  
pp. 17-43 ◽  
Author(s):  
Tsukasa Yoshida ◽  
Jingbo Zhang ◽  
Daisuke Komatsu ◽  
Seiichi Sawatani ◽  
Hideki Minoura ◽  
...  

2007 ◽  
Vol 1015 ◽  
Author(s):  
Congji Zha ◽  
Xinshi Luo ◽  
Anna Samoc ◽  
Andrei Rode ◽  
Barry Luther-Davies

AbstractDisperse Red 1 (DR1) doped TiO2-SiO2 inorganic-organic hybrid polymers were prepared by an anhydrous sol-gel process and second harmonic generation (SHG) of the fundamental 1053nm in these polymeric thin films was measured using Maker-fringe method. The nonlinear optical activity of DR1 in the thin films was studied by corona poling at different temperature (from room temperature to 140°C), and the stability of SHG after switching off corona power was evaluated by analyzing the SHG decay dynamics. Experimental results showed that the stability of the SHG of DR1 significantly increases with the cross-linkage degree of the TiO2SiO2 hybrid polymer network, and that the second harmonic coefficient d33 increases as the DR1 concentration increases. TiO2-doping can promote the polymerization of unsaturated C=C double bonds in the hybrid thin films during in-situ hot poling, enhancing the cross-linkage of the network of the hybrid material, and resulting in a great improvement of the stability of SHG. The excellent stability of second harmonic generation in the hybrid polymer thin films suggests that TiO2-doped inorganic-organic hybrid polymer is promising for chromophore doping for nonlinear optical applications.


RSC Advances ◽  
2015 ◽  
Vol 5 (86) ◽  
pp. 70238-70243 ◽  
Author(s):  
Yu Chen ◽  
Jinhui Wang ◽  
Jing Li ◽  
Xinxin Li ◽  
Shuo Wei

The inner filter effect (IFE) for Mn2+luminescence of (ZnS:Mn)2·octylamine hybrid thin film was investigated and verified by detecting three selected environmental contaminant species, which indicated that it was a good IFE-based fluorescence sensor.


2014 ◽  
Vol 50 (65) ◽  
pp. 9176-9178 ◽  
Author(s):  
Debabrata Sarkar ◽  
Dereje Hailu Taffa ◽  
Sergey Ishchuk ◽  
Ori Hazut ◽  
Hagai Cohen ◽  
...  

Tailor-made metal oxide (MO) thin films with controlled compositions, electronic structures, and architectures are obtained via molecular layer deposition (MLD) and solution treatment.


RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 103412-103417 ◽  
Author(s):  
Z. Giedraityte ◽  
L.-S. Johansson ◽  
M. Karppinen

Atomic/molecular layer deposition (ALD/MLD) processes based on Eu(thd)3 and three different aromatic organic acids with O and N donors as precursors are systematically investigated for the growth of Eu-based inorganic–organic thin-film phosphors.


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