Polyoxometalate–anatase TiO2 composites are introduced into the photoanode of dye-sensitized solar cells to retard the recombination and increase the electron lifetime

2013 ◽  
Vol 42 (8) ◽  
pp. 2691 ◽  
Author(s):  
Shi-Ming Wang ◽  
Lin Liu ◽  
Wei-Lin Chen ◽  
En-Bo Wang ◽  
Zhong-Min Su
2013 ◽  
Vol 1493 ◽  
pp. 121-126
Author(s):  
Matthew J. Carnie ◽  
Cecile Charbonneau ◽  
Matthew Davies ◽  
Ian Mabbett ◽  
Trystan Watson ◽  
...  

ABSTRACTWith the application of near-infrared radiation (NIR), TiO2 films for dye-sensitized solar cells (DSCs) on metallic substrates can be sintered in just 12.5 s. The photovoltaic performance of devices made with NIR sintered films match those devices made with conventionally sintered films prepared by heating for 1800 s. Here we characterise the electron transport, electron lifetime and phase-morphological properties of ultrafast NIR sintered films, using impedance spectroscopy, transient photovoltage decay and x-ray diffraction measurements. An important factor in NIR processing of TiO2 films is the peak metal temperature (PMT) and we show that during the 12.5 second heat treatment that a PMT of around 635 °C gives near identical electron transport, electron lifetime and morphological properties, as well comparable photovoltaic performance to a conventionally sintered (500 °C, 30 mins) film. What is perhaps most interesting is that the rapid heating of the TiO2 (to temperatures of up to 785°C) does not lead to a large scale rutile phase transition. As such photovoltaic performance of resultant DSC devices is maintained even though the TiO2 has been at temperatures which traditionally would have reduced cell photocurrents via anatase-to-rutile phase transition.


2015 ◽  
Vol 3 (6) ◽  
pp. 3066-3073 ◽  
Author(s):  
Yandong Duan ◽  
Jiaxin Zheng ◽  
Nianqing Fu ◽  
Yanyan Fang ◽  
Tongchao Liu ◽  
...  

Al-doping of SnO2photoanodes can simultaneously improve conduction band and electron lifetime of high-performance dye-sensitized solar cells.


RSC Advances ◽  
2015 ◽  
Vol 5 (107) ◽  
pp. 88052-88058 ◽  
Author(s):  
Zhisheng Chai ◽  
Jiuwang Gu ◽  
Javid Khan ◽  
Yufei Yuan ◽  
Lianhuan Du ◽  
...  

Thin, lightweight and flexible dye-sensitized solar cells (DSSCs) using three different kinds of TiO2 nanostructures grown on Ti meshes as photoanodes have been fabricated.


2013 ◽  
Vol 111 ◽  
pp. 137-142 ◽  
Author(s):  
Andrea Lamberti ◽  
Adriano Sacco ◽  
Stefano Bianco ◽  
Marzia Quaglio ◽  
Diego Manfredi ◽  
...  

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