Bottom-up synthesis of coordination polymers based on carborane backbones and Cu2(CO2)4 paddle-wheel: ligand metathesis with metallotecons

2012 ◽  
Vol 41 (38) ◽  
pp. 11657 ◽  
Author(s):  
Sheng-Li Huang ◽  
Lin-Hong Weng ◽  
Guo-Xin Jin
Keyword(s):  
Coordination Polymers ◽  
Bottom Up ◽  
Paddle Wheel

Anion and solvent controlled growth of crystalline and amorphous zinc(II) coordination polymers and a molecular complex

2021 ◽  
Author(s):  
Claire Deville ◽  
Henrik Særkjær Jeppesen ◽  
Vickie McKee ◽  
Nina Lock
Keyword(s):  
Coordination Polymers ◽  
Molecular Complex ◽  
Research Field ◽  
Metal Coordination ◽  
Controlled Growth ◽  
Bottom Up ◽  
One Dimensional

Controlled bottom-up synthesis of amorphous coordination polymers with tailored metal coordination is a research field in its infancy. In this study, synthesis control was achieved to selectively prepare one-dimensional (1D)...

Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units

CrystEngComm ◽  
2019 ◽  
Vol 21 (15) ◽  
pp. 2524-2533 ◽  
Author(s):  
Anastasia M. Cheplakova ◽  
Konstantin A. Kovalenko ◽  
Denis G. Samsonenko ◽  
Andrey S. Vinogradov ◽  
Victor M. Karpov ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Coordination Polymers ◽  
Structural Diversity ◽  
Paddle Wheel

Certain modifications of the synthetic conditions lead to 6 novel coordination polymers, thus enriching the coordination chemistry of perfluorinated ligands.

Bottom-Up Construction of POM-Based Macrostructures: Coordination Assembled Paddle-Wheel Macroclusters and Their Vesicle-like Supramolecular Aggregation in Solution

2013 ◽  
Vol 135 (45) ◽  
pp. 17155-17160 ◽  
Author(s):  
Yi Zhu ◽  
Panchao Yin ◽  
Fengping Xiao ◽  
Dong Li ◽  
Emily Bitterlich ◽  
...  
Keyword(s):  
Bottom Up ◽  
Paddle Wheel ◽  
Supramolecular Aggregation

Two novel 3D lanthanide supramolecular coordination polymers constructed from paddle wheel SBUs and hydrogen bonding: synthesis, structures and properties

RSC Advances ◽  
2014 ◽  
Vol 4 (59) ◽  
pp. 30963-30967 ◽  
Author(s):  
Qipeng Li ◽  
Shaowu Du
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Luminescent Property ◽  
Temperature Dependent ◽  
Paddle Wheel ◽  
Structures And Properties ◽  
Supramolecular Coordination

Two novel 3D lanthanide supramolecular coordination polymers with lanthanide paddle wheel SBUs were synthesized through in situ generation of formate anions. Their structure and temperature dependent luminescent property are investigated.

Synthesis, Structure and Luminescent Properties of Rare Earth Coordination Polymers Constructed from Paddle-Wheel Building Blocks

2005 ◽  
Vol 44 (11) ◽  
pp. 3850-3855 ◽  
Author(s):  
Xiaodan Guo ◽  
Guangshan Zhu ◽  
Qianrong Fang ◽  
Ming Xue ◽  
Ge Tian ◽  
...  
Keyword(s):  
Rare Earth ◽  
Coordination Polymers ◽  
Luminescent Properties ◽  
Building Blocks ◽  
Paddle Wheel ◽  
Rare Earth Coordination

Coordination Polymers Constructed from Paddle-Wheel Building Units

2002 ◽  
Vol 166 (1) ◽  
pp. 213-218 ◽  
Author(s):  
Kjell Ove Kongshaug ◽  
Helmer Fjellvåg
Keyword(s):  
Coordination Polymers ◽  
Paddle Wheel

scholarly journals Rational Design of Carborane-Based Cu2-paddle wheel Coordination Polymers for Increased Hydrolytic Stability

2022 ◽  
Author(s):  
Zhen Li ◽  
Duane Choquesillo-Lazarte ◽  
Julio Fraile ◽  
Clara Vinas ◽  
Francesc Teixidor ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Rational Design ◽  
Hydrolytic Stability ◽  
Paddle Wheel

A new unsymmetric carborane based dicarboxylic linker provided a 1D Cu2-paddle wheel coordination polymer (2) with much higher hydrolytic stability than the corresponding 2D Cu2-paddle wheel polymer (1), obtained from...

scholarly journals Single and Double-Stranded 1D-Coordination Polymers with 4′-(4-Alkyloxyphenyl)-3,2′:6′,3″-terpyridines and {Cu2(μ-OAc)4} or {Cu4(μ3-OH)2(μ-OAc)2(μ3-OAc)2(AcO-κO)2} Motifs

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 318 ◽  
Author(s):  
Dalila Rocco ◽  
Giacomo Manfroni ◽  
Alessandro Prescimone ◽  
Y. Maximilian Klein ◽  
Dariusz J. Gawryluk ◽  
...  
Keyword(s):  
Crystal Lattice ◽  
Coordination Polymers ◽  
Polymer Backbone ◽  
Paddle Wheel ◽  
Tetranuclear Clusters

Five coordination polymers formed from combinations of copper(II) acetate and 4′-(4-alkyloxyphenyl)-3,2′:6′,3″-terpyridines with methoxy (1), n-butoxy (2), n-pentyloxy (3) and n-heptyloxy (4) substituents are reported. Reaction of 1 with Cu(OAc)2∙H2O leads to the 1D-polymer [Cu2(μ-OAc)4(1)]n in which {Cu2(μ-OAc)4} paddle-wheel units are connected by ligands 1, or [{Cu4(μ3-OH)2(μ-OAc)2(μ3-OAc)2(AcO-κO)2(1)2}·2MeOH]n in which centrosymmetric tetranuclear clusters link pairs of ligands 1 to give a double-stranded 1D-polymer. Layering solutions of Cu(OAc)2∙H2O (in MeOH) over 2, 3 or 4 (in CHCl3) leads to the assembly of the 1D-polymers [2{Cu2(μ-OAc)4(2)}·1.25MeOH]n, [Cu2(μ-OAc)4(3)]n and [{Cu2(μ-OAc)4(4)}·0.2CHCl3]n. In all compounds, the 3,2′:6′,3″-tpy unit coordinates only through the outer pyridine rings, but the conformation of the 3,2′:6′,3″-tpy responds to changes in the length of the alkyloxy tails leading to changes in the conformation of the polymer backbone and in the packing of the chains in the crystal lattice in the chains featuring {Cu2(μ-OAc)4} paddle-wheel linkers.

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