Photolability of NO in designed metal nitrosyls with carboxamido-N donors: a theoretical attempt to unravel the mechanism

2012 ◽  
Vol 41 (16) ◽  
pp. 4726 ◽  
Author(s):  
Nicole L. Fry ◽  
Pradip K. Mascharak
Keyword(s):  
Metal Nitrosyls

The Electronic Structures of Metal Nitrosyls and Carbonyls

1962 ◽  
Vol 84 (17) ◽  
pp. 3404-3405 ◽  
Author(s):  
Harry B. Gray ◽  
Ivan. Bernal ◽  
Ernst. Billig
Keyword(s):  
Electronic Structures ◽  
Metal Nitrosyls

Transition metal nitrosyls as nitrosylation agents

1985 ◽  
Vol 281 (2-3) ◽  
pp. 263-272 ◽  
Author(s):  
Peter Oltmanns ◽  
Dieter Rehder
Keyword(s):  
Transition Metal ◽  
Metal Nitrosyls

ChemInform Abstract: THE KINETIC OF THE (15)NO EXCHANGE WITH TRANSITION METAL NITROSYLS

1974 ◽  
Vol 5 (22) ◽  
pp. no-no
Author(s):  
G. INNORTA ◽  
S. TORRONI ◽  
A. FOFFANI
Keyword(s):  
Transition Metal ◽  
Metal Nitrosyls

Light-Induced Metastable Linkage Isomers of Transition Metal Nitrosyls

1999 ◽  
Vol 21 (1-3) ◽  
pp. 131-148 ◽  
Author(s):  
Dmitry V. Fomitchev ◽  
Philip Coppens
Keyword(s):  
Transition Metal ◽  
Linkage Isomers ◽  
Metal Nitrosyls

Interactions of nitric oxide and organic nitroso compounds with metalloporphyrins and heme

2000 ◽  
Vol 04 (04) ◽  
pp. 354-357 ◽  
Author(s):  
GEORGE B. RICHTER-ADDO
Keyword(s):  
Nitric Oxide ◽  
Excited State ◽  
Electronic Properties ◽  
Ground State ◽  
Bond Formation ◽  
Metal Center ◽  
Nitroso Compounds ◽  
Model Compounds ◽  
Axial Ligands ◽  
Metal Nitrosyls

The chemistry of nitric oxide (NO) has taken on new dimensions since the discovery, about a decade ago, of a myriad of biological events that NO participates in. Many of the foundations of metal-NO chemistry were laid out earlier by inorganic chemists and biochemists investigating the structures and electronic properties of the heme-NO moiety or its model compounds. Certainly, the persistent work over the last three decades by chemists working with metal nitrosyls has paid off. Current areas of research in heme-NO chemistry include (i) how the NO group approaches and binds to the metal center (or how it dissociates from the metal center); (ii) the ground state and excited state geometries of the metal-NOfragment; (iii) effects of the trans axial ligands on NO orientation and/or dissociation; and (iv) N-N bond formation from NO molecules catalyzed by heme groups.

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