Nickel catalysts supported on calcium titanate for enhanced CO methanation

2013 ◽  
Vol 3 (2) ◽  
pp. 490-499 ◽  
Author(s):  
Chunmiao Jia ◽  
Jiajian Gao ◽  
Jing Li ◽  
Fangna Gu ◽  
Guangwen Xu ◽  
...  
2021 ◽  
Vol 35 (4) ◽  
pp. 3307-3314
Author(s):  
Yahong Han ◽  
Jinxian Zhao ◽  
Yanhong Quan ◽  
Shunan Yin ◽  
Shiping Wu ◽  
...  

2011 ◽  
Vol 52 (5) ◽  
pp. 749-755 ◽  
Author(s):  
Luu Cam Loc ◽  
Nguyen Manh Huan ◽  
N. A. Gaidai ◽  
Ho Si Thoang ◽  
N. V. Nekrasov ◽  
...  

2012 ◽  
Vol 51 (31) ◽  
pp. 10345-10353 ◽  
Author(s):  
Jiajian Gao ◽  
Chunmiao Jia ◽  
Jing Li ◽  
Fangna Gu ◽  
Guangwen Xu ◽  
...  

2014 ◽  
Vol 486 ◽  
pp. 143-149 ◽  
Author(s):  
J. Barrientos ◽  
M. Lualdi ◽  
M. Boutonnet ◽  
S. Järås

2018 ◽  
Vol 221 ◽  
pp. 413-421 ◽  
Author(s):  
M.V. Konishcheva ◽  
D.I. Potemkin ◽  
P.V. Snytnikov ◽  
O.A. Stonkus ◽  
V.D. Belyaev ◽  
...  

2015 ◽  
Vol 502 ◽  
pp. 276-286 ◽  
Author(s):  
J. Barrientos ◽  
M. Lualdi ◽  
R. Suárez París ◽  
V. Montes ◽  
M. Boutonnet ◽  
...  

2014 ◽  
Vol 4 (8) ◽  
pp. 2508-2511 ◽  
Author(s):  
Aihua Chen ◽  
Toshihiro Miyao ◽  
Kazutoshi Higashiyama ◽  
Mashiro Watanabe

Ni/mesoporous ZrO2, without precious metals, exhibits high performance for selective CO methanation at a wide range of working temperatures and superior long-term stability.


2011 ◽  
Vol 236-238 ◽  
pp. 829-834 ◽  
Author(s):  
Qi Hai Liu ◽  
Lie Wen Liao ◽  
Xin Hua Zhou ◽  
Quo Qiang Yin

Mesoporous nano zirconian was prepared by the self-assembly route using hexadecyltrimethyl ammonium bromide (CTAB) surfactant and employed as support for Nickel catalysts for selective methanation of CO. The CO methanation catalytic performance of the synthesized mesoporous nano zirconia-supported Ni-based catalysts was investigated, and the catalysts were charactered by TG/DSC, BET and XRD techniques. The results showed that, when the Ni loading was under 7.5 wt%, almost all the nickle species were in the form of nanoscale crystallites that finely distributed on the mosoporous nano zirconian surface. These well dispersive nickle species presented unique high activity and selectivity for CO methanation. For all the catalysts studied, the 7.5 wt%Ni/ZrO2catalyst was the most effective one, which showed a higher than 99% of CO conversion in the CO/CO2competitive methanation reactions over the temperature interval of 260~280°C, while the CO2conversion was held at the low level.


2018 ◽  
Vol 115 ◽  
pp. 40-44 ◽  
Author(s):  
Hamidreza Arandiyan ◽  
Ghasem Kasaeian ◽  
Behzad Nematollahi ◽  
Yuan Wang ◽  
Hongyu Sun ◽  
...  

Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 415 ◽  
Author(s):  
Luciano Atzori ◽  
Elisabetta Rombi ◽  
Daniela Meloni ◽  
Maria Franca Sini ◽  
Roberto Monaci ◽  
...  

Supported nickel catalysts were synthesized, characterized, and employed in the carbon oxides co-methanation process. Five NiO/CeO2-ZrO2 mixed oxides, with the same Ni content and different Ce/Zr molar ratios, were prepared by the soft-template method. They were characterized through ICP-AES, N2 adsorption, XRD, and TPR. Reduced Ni/CeO2-ZrO2 catalysts were obtained by submitting the oxide systems to reduction treatment in H2 at 400 °C. They were characterized by XRD, H2-TPD, and CO2 adsorption microcalorimetry and their catalytic performances in the carbon oxides co-methanation were investigated. Catalytic tests were performed in a fixed-bed continuous-flow microreactor at atmospheric pressure. The effect of experimental conditions (reaction temperature, space velocity, reactants molar ratio) was also studied. Almost complete CO conversion was obtained on any catalyst, whereas CO2 conversion was much lower and increased with Ce content, at least up to Ce/Zr = 1. The beneficial effect of the Ce content could be related to the increased NiO reducibility and to the higher ability to adsorb and activate CO2. However, at high Ce/Zr ratios, it is probably counterbalanced by an interplay of reactions involving CO and CO2.


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