Solid-state single-crystal-to-single-crystal transformation from a 2D layer to a 3D framework mediated by lattice iodine release

2012 ◽  
Vol 48 (63) ◽  
pp. 7859 ◽  
Author(s):  
Yuan-Chun He ◽  
Jin Yang ◽  
Guo-Cheng Yang ◽  
Wei-Qiu Kan ◽  
Jian-Fang Ma
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Crystal Transformation ◽  
Iodine Release ◽  
3D Framework

scholarly journals Solid-State Conformational Flexibility at Work: Energetic Landscape of a Single Crystal-to-Single Crystal Transformation in a Cyclic Hexapeptoid

2021 ◽  
Vol 21 (2) ◽  
pp. 897-907
Author(s):  
Giovanni Pierri ◽  
Marta Corno ◽  
Eleonora Macedi ◽  
Maria Voccia ◽  
Consiglia Tedesco
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Conformational Flexibility ◽  
Crystal Transformation

A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

2020 ◽  
Vol 56 (1) ◽  
pp. 133-136
Author(s):  
Xiao-Peng Sun ◽  
Zheng Tang ◽  
Zi-Shuo Yao ◽  
Jun Tao
Keyword(s):  
Single Crystal ◽  
Spin State ◽  
Spin Crossover ◽  
Crystal Transformation ◽  
State Switching ◽  
One Step ◽  
3D Framework

A homochiral 3D mechanically interlocked framework based on 1D loops is presented, which shows reversible single-crystal-to-single-crystal transformation and enables the interconversion between one-step and two-step spin crossover behaviors.

Monocrystalline mesoporous metal oxide with perovskite structure: a facile solid-state transformation of a coordination polymer

2014 ◽  
Vol 50 (89) ◽  
pp. 13849-13852 ◽  
Author(s):  
Li Xu ◽  
Fan-Xing Bu ◽  
Ming Hu ◽  
Chuan-Yin Jin ◽  
Dong-Mei Jiang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Metal Oxide ◽  
Single Crystal ◽  
Perovskite Structure ◽  
State Transformation ◽  
Solid State Transformation ◽  
Crystal Transformation ◽  
Mesoporous Metal ◽  
Mesoporous Metal Oxide

Monocrystalline mesoporous BiFeO3 crystals were obtained via a multi-step single-crystal to single-crystal transformation of a coordination polymer, Bi[Fe(CN)6]·4H2O.

Two Consecutive Magneto-Structural Gas-Solid Transformations with Single-Crystal Retention in Non-Porous Molecular Materials

2018 ◽  
Author(s):  
Julia Miguel-Donet ◽  
Javier López-Cabrelles ◽  
Nestor Calvo Galve ◽  
Eugenio Coronado ◽  
Guillermo Minguez Espallargas
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Structural Rearrangement ◽  
Magnetic Behaviour ◽  
Porous Solids ◽  
Potential Applications ◽  
Hcl Gas ◽  
Porous Coordination Polymer ◽  
Gas Molecules ◽  
Magnetostructural Transformation

<p>Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behaviour. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement which is also accompanied by modification in the magnetic path between the metal centres. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.</p>

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

Sign in / Sign up

Export Citation Format

Share Document