SBA-15-functionalized sulfonic acid confined acidic ionic liquid: a powerful and water-tolerant catalyst for solvent-free esterifications

2012 ◽  
Vol 48 (27) ◽  
pp. 3327 ◽  
Author(s):  
Babak Karimi ◽  
Majid Vafaeezadeh
Keyword(s):  
Ionic Liquid ◽  
Sulfonic Acid ◽  
Solvent Free ◽  
Acidic Ionic Liquid

Brønsted acidic ionic liquid-catalyzed tandem reaction: an efficient approach towards regioselective synthesis of pyrano[3,2-c]coumarins under solvent-free conditions bearing lower E-factors

2017 ◽  
Vol 19 (14) ◽  
pp. 3282-3295 ◽  
Author(s):  
Sachinta Mahato ◽  
Sougata Santra ◽  
Rana Chatterjee ◽  
Grigory V. Zyryanov ◽  
Alakananda Hajra ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Sulfonic Acid ◽  
Solvent Free ◽  
Regioselective Synthesis ◽  
Tandem Reaction ◽  
Efficient Approach ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Tandem Cyclization

1-Butane sulfonic acid-3-methylimidazolium tosylate, [BSMIM]OTs, is found to be a remarkable catalyst for the tandem cyclization of 4-hydroxycoumarin with chalcones.

1, 1’-Sulfinyldiethylammonium Bis (Hydrogen Sulfate) as a Recyclable Dicationic Ionic Liquid Catalyst for the Efficient Solvent-free Synthesis of 3, 4-Dihydropyrimidin-2(1H)-ones via Biginelli Reaction

2020 ◽  
Vol 23 (2) ◽  
pp. 157-167
Author(s):  
Zainab Ehsani-Nasab ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Biginelli Reaction ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
Hydrogen Sulfate ◽  
One Pot ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Dicationic Ionic Liquid

Objective: A facile and efficient method for synthesis of 3, 4-dihydropyrimidin-2(1H)-ones via Biginelli reaction catalyzed by a novel dicationic Brönsted acidic ionic liquid, [(EtNH2)2SO][HSO4]2, has been successfully developed. Material and Method:: 3, 4-Dihydropyrimidin-2(1H)-ones were synthesized through one-pot condensation of aromatic aldehydes, ethyl acetoacetate, and urea under solvent-free conditions using [(EtNH2)2SO][HSO4]2 as a novel catalyst. The progress of the reaction was monitored by thin-layer chromatography (ethyl acetate / n-hexane = 1 / 5). The products have been characterized by IR, 1H NMR, 13C NMR, and also by their melting points. Results: In this research, a library of dihydropyrimidinone derivatives was synthesized via Biginelli reaction under solvent-free conditions at 120oC using [(EtNH2)2SO][HSO4]2 as a catalyst. Various aromatic aldehydes, as well as heteroaromatic aldehydes, were employed, affording good to high yields of the corresponding products and illustrating the substrate generality of the present method. In addition, the prepared dicationic Brönsted acidic ionic liquid can be easily recovered and reused. Conclusion: 1, 1’-Sulfinyldiethylammonium bis (hydrogen sulfate), as a novel dicationic ionic liquid, can act as a highly efficient catalyst for the synthesis of 3, 4-dihydropyrimidin-2(1H)-ones under solvent-free conditions.

Synthesis and Characterization of a Novel Ionic Liquid Based on N,N,N,N-tetramethylethylenediamine and its Application in the Synthesis of 1,8-dioxo-octahydro Xanthenes

2018 ◽  
Vol 21 (7) ◽  
pp. 526-532 ◽  
Author(s):  
Zahra Abdi Piralghar ◽  
Mohammad Mahmoodi Hashemi ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Chlorosulfonic Acid ◽  
Solvent Free ◽  
Aryl Aldehydes ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Aryl Aldehyde ◽  
High Yields

Aim and Objective: In this work, we synthesized and characterized a novel Brönsted acidic ionic liquid from the reaction of N, N, N’, N’-tetramethylethylenediamine with chlorosulfonic acid and explored its catalytic activity in 1, 8-dioxo-octahydroxanthenes synthesis. Materials and Methods: Dimedone, aryl aldehydes, and the ionic liquid as the catalyst were reacted under solvent-free conditions. The progressive of the reaction was monitored by a thin layer of chromatography (ethyl acetate/n-hexane = 1/5). All products were characterized as the basis of their spectra data and melting point by comparison with those reported in the literature. Results: The prepared ionic liquid was successfully applied in the synthesis of 1, 8-dioxooctahydroxanthenes in good to high yields on the reaction of aryl aldehyde and dimedone at 120oC under solvent-free conditions. Conclusion: This research demonstrates that the catalyst is impressive for 1, 8-dioxo-octahydroxanthenes synthesis under solvent-free conditions.

Enhanced sensing performance of carboxyl graphene–ionic liquid attached ionic polymer–metal nanocomposite based polymer strain sensors

2018 ◽  
Vol 6 (31) ◽  
pp. 8395-8404 ◽  
Author(s):  
Varij Panwar ◽  
Gopinathan Anoop
Keyword(s):  
Ionic Liquid ◽  
Sulfonic Acid ◽  
Strain Sensors ◽  
Ionic Polymer ◽  
Blend Membrane ◽  
Acidic Ionic Liquid ◽  
Bending Strain ◽  
Polymer Metal ◽  
Polystyrene Sulfonic Acid ◽  
Metal Nanocomposite

Here, we show that biocompatible IPMNC sensors based on a carboxyl graphene–acidic ionic liquid–polyvinylpyrrolidone–polystyrene sulfonic acid ionic blend membrane can generate a high sensing current (6 mA cm−2) with a bending strain of 0.009.

scholarly journals Immobilization of Lewis acidic ionic liquid on perlite nanoparticle surfaces as a highly efficient solid acid catalyst for the solvent-free synthesis of xanthene derivatives

RSC Advances ◽  
2019 ◽  
Vol 9 (35) ◽  
pp. 19940-19948 ◽  
Author(s):  
L. Moradi ◽  
M. Mirzaei
Keyword(s):  
Ionic Liquid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Solvent Free ◽  
High Yield ◽  
Efficient Catalyst ◽  
Acidic Ionic Liquid ◽  
Highly Efficient ◽  
Xanthene Derivatives ◽  
Lewis Acidic Ionic Liquid

Perlite nanoparticles were prepared, modified with Lewis acidic ionic liquid, and used as a highly efficient catalyst for the eco-friendly, solvent free and high yield synthesis of xanthenesviaa multicomponent reaction.

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