Application of the dissociative electron transfer theory and its extension to the case of in-cage interactions in the electrochemical reduction of arenesulfonyl chlorides

2012 ◽  
Vol 14 (1) ◽  
pp. 113-124 ◽  
Author(s):  
Abdelaziz Houmam ◽  
Emad M. Hamed
Keyword(s):  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Dissociative Electron Transfer ◽  
Transfer Theory ◽  
Electron Transfer Theory

Reaction rates in the phenomenological adiabatic excited-state electron-transfer theory

1991 ◽  
Vol 95 (25) ◽  
pp. 10485-10492 ◽  
Author(s):  
Keisuke Tominaga ◽  
Gilbert C. Walker ◽  
Tai Jong Kang ◽  
Paul F. Barbara ◽  
Teresa Fonseca
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Reaction Rates ◽  
Transfer Theory ◽  
State Electron ◽  
Electron Transfer Theory

scholarly journals Electron-transfer theory in question

Nature ◽  
1988 ◽  
Vol 333 (6169) ◽  
pp. 114-114 ◽  
Author(s):  
Jim Barber
Keyword(s):  
Electron Transfer ◽  
Transfer Theory ◽  
Electron Transfer Theory

ELECTRON TRANSFER THEORY REVISITED: QUANTUM SOLVATION EFFECT

2006 ◽  
Vol 05 (03) ◽  
pp. 685-692 ◽  
Author(s):  
PING HAN ◽  
RUI-XUE XU ◽  
PING CUI ◽  
YAN MO ◽  
GUOZHONG HE ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Relaxation Time ◽  
Close Relation ◽  
Longitudinal Relaxation Time ◽  
Inverse Temperature ◽  
Exact Theory ◽  
Transfer Theory ◽  
Electron Transfer Theory ◽  
Rate Processes ◽  
Classical Picture

The effect of solvation on ET rate processes has been investigated on the basis of the exact theory constructed in J. Phys. Chem. B110:11438, 2006. The nature of solvation has been studied in close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics have been analyzed accordingly. The classical picture of solvation has been found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.

Dissociative Electron Transfer to Dihaloalkanes. Electrochemical Reduction of 1,3-Dihaloadamantanes, 1,4-Dihalobicyclo[2.2.2]octanes, and 1,3-Dihalobicyclo[1.1.1]pentanes

1994 ◽  
Vol 116 (11) ◽  
pp. 4653-4659 ◽  
Author(s):  
William Adcock ◽  
Christopher I. Clark ◽  
Abdelaziz Houmam ◽  
Alexander R. Krstic ◽  
Jean Pinson ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Dissociative Electron Transfer

The Electrical Properties of Thin Films of TiNx and TiCx

1975 ◽  
Vol 30 (12) ◽  
pp. 1661-1666 ◽  
Author(s):  
P. J. P. De Maayer ◽  
J. D. Mackenzie
Keyword(s):  
Thin Films ◽  
Electron Transfer ◽  
Electron Beam ◽  
Electrical Properties ◽  
Transport Properties ◽  
Electron Concentration ◽  
Defect Structure ◽  
Electron Beam Evaporation ◽  
Transfer Theory ◽  
Electron Transfer Theory

Abstract Thin films of metallically conductive titanium mononitride and carbide were prepared by means of electron beam evaporation. The composition of the samples could be changed over appreciable ranges by introducing nitrogen in the system or adding carbon to the pure starting material, respectively. The transport properties of the resulting compounds were studied as a function of nonstoichiometry and defect structure. A plausible explanation for the different behavior of the films compared to corresponding bulk samples is given and a correlation between the change in electron concentration and the electron transfer theory is presented.

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