Dissociative Electron Transfer to Dihaloalkanes. Electrochemical Reduction of 1,3-Dihaloadamantanes, 1,4-Dihalobicyclo[2.2.2]octanes, and 1,3-Dihalobicyclo[1.1.1]pentanes

1994 ◽  
Vol 116 (11) ◽  
pp. 4653-4659 ◽  
Author(s):  
William Adcock ◽  
Christopher I. Clark ◽  
Abdelaziz Houmam ◽  
Alexander R. Krstic ◽  
Jean Pinson ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Dissociative Electron Transfer

scholarly journals Electrochemical Reduction of G3-Factor Endoperoxide and Its Methyl Ether: Evidence for a Competition between Concerted and Stepwise Dissociative Electron Transfer

2007 ◽  
Vol 13 (4) ◽  
pp. 1174-1179 ◽  
Author(s):  
Fadia Najjar ◽  
Christiane André-Barrès ◽  
Michel Baltas ◽  
Corinne Lacaze-Dufaure ◽  
David C. Magri ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Methyl Ether ◽  
Dissociative Electron Transfer

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Dissociative electron transfer of copper(ii) complexes of glycyl(glycyl/alanyl)tryptophan in vacuo: IRMPD action spectroscopy provides evidence of transition from zwitterionic to non-zwitterionic peptide structures

2020 ◽  
Vol 22 (23) ◽  
pp. 13084-13091 ◽  
Author(s):  
Yinan Li ◽  
Mengzhu Li ◽  
Daniel M. Spencer ◽  
Justin Kai-Chi Lau ◽  
Jonathan Martens ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Unpaired Electron ◽  
Dissociative Electron Transfer ◽  
Action Spectroscopy

Non-zwitterionic π-centered [GGWπ]˙+ is formed from zwitterionic [CuII(dien)GGW]˙2+ through dissociative one-electron transfer involving proton and unpaired electron migrations.

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