Solvothermal syntheses, crystal structures, and characterizations of a series of one-dimensional organic-containing gallium polyselenides

CrystEngComm ◽  
2011 ◽  
Vol 13 (20) ◽  
pp. 6206 ◽  
Author(s):  
Wei-Wei Xiong ◽  
Jian-Rong Li ◽  
Mei-Ling Feng ◽  
Xiao-Ying Huang
2011 ◽  
Vol 66 (9) ◽  
pp. 877-881
Author(s):  
Chao Xu ◽  
Jing-Jing Zhang ◽  
Taike Duan ◽  
Qun Chen ◽  
Qian-Feng Zhang

Two new selenogallates, [bappH2][Ga2Se4] (1) (bapp = 1,4-bis(3-aminopropyl)-piperazine) and [Mn(en)3][Ga2Se5] (2) (en = ethylenediamine), have been synthesized under solvothermal conditions and structurally characterized by single-crystal X-ray diffraction. Compounds 1 and 2 contain one-dimensional polymeric chains {[Ga2Se4]2−}∞ and {[Ga2Se5]2−}∞, respectively. The negative charges of the polymeric chains are balanced by a protonated 1,4-bis(3-aminopropyl)piperazine cation in 1 and by the metal-amine complex cations [Mn(en)3]2+ in 2. TGA analyses have shown that compound 2 is thermally more stable than compound 1.


2010 ◽  
Vol 40 (6) ◽  
pp. 496-500 ◽  
Author(s):  
Yong Zhang ◽  
Jian Zhou ◽  
Ai-Bin Tang ◽  
Guo-Qing Bian ◽  
Jie Dai

2017 ◽  
Vol 2 (24) ◽  
pp. 7303-7308 ◽  
Author(s):  
Xue-Wei Li ◽  
Han-Zhong Zhang ◽  
Guang-Feng Hou ◽  
Xin Xu ◽  
Ying-Hui Yu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document