Thermally-activated chemiluminescent squaraine rotaxane endoperoxide with green emission

2011 ◽  
Vol 47 (45) ◽  
pp. 12352 ◽  
Author(s):  
Carleton G. Collins ◽  
Jeffrey M. Baumes ◽  
Bradley D. Smith
Keyword(s):  
Green Emission ◽  
Thermally Activated ◽  
Squaraine Rotaxane

Star-shaped thermally activated delayed fluorescence emitters with a tri-armed arylsulfonic acceptor for efficient solution processed organic light emitting diodes

2020 ◽  
Vol 8 (16) ◽  
pp. 5580-5586 ◽  
Author(s):  
Ran Xiao ◽  
Yepeng Xiang ◽  
Xiaosong Cao ◽  
Nengquan Li ◽  
Taian Huang ◽  
...  
Keyword(s):  
Efficient Solution ◽  
Light Emitting Diodes ◽  
Green Emission ◽  
Delayed Fluorescence ◽  
Organic Light Emitting Diodes ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Organic Light

Two star-shaped TADF emitters bearing an arylsulfone-derived acceptor were developed for wet-processed OLEDs, with efficient blue/green emission and low roll-off.

Efficient thermally activated delayed fluorescence based on carbonitrile-substituted pyridine and carbazole

2019 ◽  
Vol 7 (44) ◽  
pp. 13754-13758 ◽  
Author(s):  
Ming Xu ◽  
Ming Liu ◽  
Ming Shi ◽  
Muhammad Umair Ali ◽  
Shibo Jiao ◽  
...  
Keyword(s):  
Green Emission ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

New thermally activated delayed fluorescence emitters based on carbonitrile-substituted pyridine and carbazole achieved efficient blue and green emission.

Thermally activated flow of β-titanium and β-titanium-hydrogen alloys

2000 ◽  
Vol 80 (12) ◽  
pp. 2813-2825
Author(s):  
O. N. Senkov, J. J. Jonas, F. H. Froes
Keyword(s):  
Thermally Activated

Growth Kinetics of Quantum Size ZnO Particles

1998 ◽  
Vol 536 ◽  
Author(s):  
E. M. Wong ◽  
J. E. Bonevich ◽  
P. C. Searson
Keyword(s):  
Growth Kinetics ◽  
Ostwald Ripening ◽  
Chemical Potential ◽  
Colloidal Suspensions ◽  
Green Emission ◽  
Blue Shift ◽  
Constant Current ◽  
Mass Model ◽  
Zno Particles ◽  
Kinetics Of

AbstractColloidal chemistry techniques were used to synthesize ZnO particles in the nanometer size regime. The particle aging kinetics were determined by monitoring the optical band edge absorption and using the effective mass model to approximate the particle size as a function of time. We show that the growth kinetics of the ZnO particles follow the Lifshitz, Slyozov, Wagner theory for Ostwald ripening. In this model, the higher curvature and hence chemical potential of smaller particles provides a driving force for dissolution. The larger particles continue to grow by diffusion limited transport of species dissolved in solution. Thin films were fabricated by constant current electrophoretic deposition (EPD) of the ZnO quantum particles from these colloidal suspensions. All the films exhibited a blue shift relative to the characteristic green emission associated with bulk ZnO. The optical characteristics of the particles in the colloidal suspensions were found to translate to the films.

Solvent Dependence of Structural Dynamics and Spin-flip Processes in 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (ortho-3CzBN)

2020 ◽  
Author(s):  
Masaki Saigo ◽  
Kiyoshi Miyata ◽  
Hajime Nakanotani ◽  
Chihaya Adachi ◽  
Ken Onda
Keyword(s):  
Dft Calculations ◽  
Excited States ◽  
Structural Changes ◽  
Photophysical Properties ◽  
Delayed Fluorescence ◽  
Time Resolved ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Solvent Dependence ◽  
Acetonitrile Solutions

We have investigated the solvent-dependence of structural changes along with intersystem crossing of a thermally activated delayed fluorescence (TADF) molecule, 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (o-3CzBN), in toluene, tetrahydrofuran, and acetonitrile solutions using time-resolved infrared (TR-IR) spectroscopy and DFT calculations. We found that the geometries of the S1 and T1 states are very similar in all solvents though the photophysical properties mostly depend on the solvent. In addition, the time-dependent DFT calculations based on these geometries suggested that the thermally activated delayed fluorescence process of o-3CzBN is governed more by the higher-lying excited states than by the structural changes in the excited states.<br>

Mass spectrometric study of allyl radical, allyl bromide and 1,5-hexadiene interactions with oxides; Cobalt suboxide Co3O4

1979 ◽  
Vol 44 (7) ◽  
pp. 2009-2014 ◽  
Author(s):  
Jana Nováková ◽  
Zdeněk Dolejšek
Keyword(s):  
Room Temperature ◽  
Allyl Bromide ◽  
Catalytic Properties ◽  
Mass Spectrometric Study ◽  
Spectrometric Study ◽  
Flow Conditions ◽  
Allyl Radical ◽  
Knudsen Flow ◽  
Thermally Activated ◽  
Radical Interaction

Products of (a) allyl radical interaction with unheated Co3O4, (b) thermally activated 1,5-hexadiene or thermally activated allyl bromide with unheated Co3O4, (c) moderately heated Co3O4 with unheated 1,5-hexadiene or allyl bromide were studied under Knudsen flow conditions. Cobalt suboxide Co3O4, a typical catalyst of deep oxidations yielded acrolein in reaction with allyl radicals as early as at the room temperature of the catalyst. A similar acrolein formation was also observed in the allyl radical interaction with other oxides exhibiting different catalytic properties. It appears that acrolein is in general the primary product of the allyl radical interaction with the oxides. The results are discussed and compared with previous data obtained with MoO3.

Effect of grain size on the vapour phase hydration of monoclinic and triclinic modifications of tricalcium silicate; role of high temperature activation

1991 ◽  
Vol 56 (10) ◽  
pp. 1993-2008
Author(s):  
S. Hanafi ◽  
G. M. S. El-Shafei ◽  
B. Abd El-Hamid
Keyword(s):  
Particle Size ◽  
Vapour Phase ◽  
Tricalcium Silicate ◽  
Active Centers ◽  
Thermally Activated ◽  
Grain Sizes ◽  
Intermediate Size ◽  
Surface Active ◽  
Temperature Activation

The hydration of tricalcium silicate (C3S) with three grain sizes of monoclinic (M) and triclinic (T) modifications and on their thermally activated samples were investigated by exposure to water vapour at 80°C for 60 days. The products were investigated by XRD, TG and N2 adsorption. The smaller the particle size the greater was the hydration for both dried and activated samples from (M). In the activated samples a hydrate with 2θ values of 38.4°, 44.6° and 48.6° could be identified. Hydration increased with particle size for the unactivated (T) samples but after activation the intermediate size exhibited enhanced hydration. Thermal treatment at 950°C of (T) samples increased the surface active centers on the expense of those in the bulk. Changes produced in surface texture upon activation and/or hydration are discussed.

Sign in / Sign up

Export Citation Format

Share Document