Photoredox catalyzed C–P bond forming reactions—visible light mediated oxidative phosphonylations of amines

2011 ◽  
Vol 47 (30) ◽  
pp. 8679 ◽  
Author(s):  
Magnus Rueping ◽  
Shaoqun Zhu ◽  
René M. Koenigs
Keyword(s):  
Visible Light ◽  
Bond Forming ◽  
Bond Forming Reactions

Dual copper- and photoredox-catalysed C(sp2)–C(sp3) coupling

2019 ◽  
Vol 55 (29) ◽  
pp. 4238-4241 ◽  
Author(s):  
Euan B. McLean ◽  
Vincent Gauchot ◽  
Sebastian Brunen ◽  
David J. Burns ◽  
Ai-Lan Lee
Keyword(s):  
Visible Light ◽  
Boronic Acids ◽  
Copper Catalysis ◽  
Photoredox Catalysis ◽  
Bond Forming ◽  
Bond Forming Reactions

The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C–C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp2)–C(sp3) cross-couplings between aryl boronic acids and benzyl bromides.

scholarly journals First use of a divalent lanthanide for visible-light-promoted photoredox catalysis

2018 ◽  
Vol 9 (5) ◽  
pp. 1273-1278 ◽  
Author(s):  
Tyler C. Jenks ◽  
Matthew D. Bailey ◽  
Jessica L. Hovey ◽  
Shanilke Fernando ◽  
Gihan Basnayake ◽  
...  
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Bond Forming ◽  
Divalent Europium ◽  
Bond Forming Reactions ◽  
Divalent Lanthanide

Divalent europium is used catalytically in visible-light-promoted photoredox bond-forming reactions.

ChemInform Abstract: [Cu(dap)2Cl] as an Efficient Visible-Light-Driven Photoredox Catalyst in Carbon-Carbon Bond-Forming Reactions.

ChemInform ◽  
2012 ◽  
Vol 43 (44) ◽  
pp. no-no
Author(s):  
Michael Pirtsch ◽  
Suva Paria ◽  
Taisuke Matsuno ◽  
Hiroyuki Isobe ◽  
Oliver Reiser
Keyword(s):  
Visible Light ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Visible Light Driven

[Cu(dap)2Cl] As an Efficient Visible-Light-Driven Photoredox Catalyst in Carbon-Carbon Bond-Forming Reactions

2012 ◽  
Vol 18 (24) ◽  
pp. 7336-7340 ◽  
Author(s):  
Michael Pirtsch ◽  
Suva Paria ◽  
Taisuke Matsuno ◽  
Hiroyuki Isobe ◽  
Oliver Reiser
Keyword(s):  
Visible Light ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Visible Light Driven

Visible-Light Photosensitized Aryl and Alkyl Decarboxylative Carbon-Heteroatom and Carbon-Carbon Bond Formations

2019 ◽  
Author(s):  
Tuhin Patra ◽  
Satobhisha Mukherjee ◽  
Jiajia Ma ◽  
Felix Strieth-Kalthoff ◽  
Frank Glorius
Keyword(s):  
Energy Transfer ◽  
Visible Light ◽  
Alkyl Radical ◽  
General Strategy ◽  
Alkyl Radicals ◽  
Bond Forming ◽  
Radical Trapping ◽  
Carbon Carbon Bond ◽  
Radical Generation ◽  
Trapping Agent

<sub>A general strategy to access both aryl and alkyl radicals by photosensitized decarboxylation of the corresponding carboxylic acids esters has been developed. An energy transfer mediated homolysis of unsymmetrical sigma-bonds for a concerted fragmentation/decarboxylation process is involved. As a result, an independent aryl/alkyl radical generation step enables a series of key C-X and C-C bond forming reactions by simply changing the radical trapping agent.</sub>

Recent Advances on C-Se Bond-forming Reactions at Low and Room Temperature

2020 ◽  
Vol 23 (28) ◽  
pp. 3206-3225 ◽  
Author(s):  
Amol D. Sonawane ◽  
Mamoru Koketsu
Keyword(s):  
Room Temperature ◽  
Bond Formation ◽  
Bond Forming ◽  
Material Chemistry ◽  
Recent Advances ◽  
Bond Forming Reactions ◽  
Bond Formation Reactions

: Over the last decades, many methods have been reported for the synthesis of selenium- heterocyclic scaffolds because of their interesting reactivities and applications in the medicinal as well as in the material chemistry. This review describes the recent numerous useful methodologies on C-Se bond formation reactions which were basically carried out at low and room temperature.

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