The reaction of methylphenylacetylene with palladium chloride

1968 ◽  
pp. 481
Author(s):  
H. Dietl ◽  
P. M. Maitlis
Keyword(s):  
Palladium Chloride

Facile and practical hydrodehalogenations of organic halides enabled by calcium hydride and palladium chloride

2021 ◽  
Author(s):  
Jingjing Gui ◽  
Xin Cai ◽  
Lingyun Chen ◽  
Yuxin Zhou ◽  
Wenjing Zhu ◽  
...  
Keyword(s):  
Palladium Chloride ◽  
Calcium Hydride ◽  
Organic Halides ◽  
Wide Range

Herein, a convenient hydrodehalogenation method was described by employing less-explored calcium hydride as the reductant. A wide range of organic halides such as aromatic bromides, aromatic chlorides, aromatic triflates, aliphatic...

Lewis Acid-Promoted Suzuki Reaction using Palladium Chloride Anchored on a Polymer as a Catalyst

2008 ◽  
Vol 61 (8) ◽  
pp. 610 ◽  
Author(s):  
Guozhi Fan ◽  
Hanjun Zhang ◽  
Siqing Cheng ◽  
Zhandong Ren ◽  
Zhijun Hu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Lewis Acid ◽  
Lewis Acids ◽  
Heterogeneous Catalysts ◽  
Suzuki Reaction ◽  
Cross Coupling ◽  
Palladium Chloride ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Recoverable Catalyst

Palladium chloride anchored on polystyrene modified by 5-amino-1,10-phenanthroline was prepared and used as an efficient recoverable catalyst for Suzuki cross-coupling reactions. The heterogeneous catalysts can be easily separated from the reaction mixture and reused for five cycles without significant Pd leaching and loss of catalytic activity. Rate enhancement in the Suzuki reaction by Lewis acids was also studied.

Extension of the Alkane Bridge in BisNHC−Palladium−Chloride Complexes. Synthesis, Structure, and Catalytic Activity

2006 ◽  
Vol 25 (22) ◽  
pp. 5409-5415 ◽  
Author(s):  
Sebastian Ahrens ◽  
Alexander Zeller ◽  
Maria Taige ◽  
Thomas Strassner
Keyword(s):  
Catalytic Activity ◽  
Palladium Chloride ◽  
Chloride Complexes ◽  
Palladium Chloride Complexes

Direct Synthesis β-Acyloxy Aldehydes from Linear Allylic Esters Using O2 as Sole Oxidant

2022 ◽  
Author(s):  
Shu-Hui Lei ◽  
Ya Zhong ◽  
Xian-Peng Cai ◽  
Qing Huang ◽  
Jian-Ping Qu ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
Palladium Chloride ◽  
Allylic Esters

A simple and practical preparation of β-O substituted aldehydes directly from linear allylic esters is developed. Using bis(benzonitrile)palladium chloride as the catalyst and O2 as sole oxidant, the tandem isomerization-...

scholarly journals Effects of Hard Surface Grinding and Activation on Electroless-Nickel Plating on Cast Aluminium Alloy Substrates

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Olawale Olarewaju Ajibola ◽  
Daniel T. Oloruntoba ◽  
Benjamin O. Adewuyi
Keyword(s):  
Aluminium Alloy ◽  
Electroless Nickel ◽  
Sodium Hypophosphite ◽  
Palladium Chloride ◽  
Alloy Sample ◽  
Sand Cast ◽  
Hard Surface ◽  
Cast Aluminium ◽  
Surface Polishing ◽  
Cylinder Piston

This work examined effects of hard surface polishing grits and activation on electroless-nickel (EN) plating on cast aluminium alloy substrates in sodium hypophosphite baths. As-received aluminium alloy sample sourced from automobile hydraulic brake master cylinder piston was melted in electric furnace and sand cast into rod. The cast samples were polished using different grits (60 μm–1200 μm) before plating. The effects on adhesion, appearance, and quantity of EN deposits on substrates were studied. Observation shows that the quantity of EN deposit is partly dependent on the alloy type and roughness of the surface of the substrates, whereas the adhesion and brightness are not solely controlled by the degree of surface polishing. The best yield in terms of adhesion and appearance was obtained from the activation in zincate and palladium chloride solutions. Higher plating rates (g/mm2/min) of 3.01E-05, 2.41E-05, and 2.90E-05 were obtained from chromate, zincate, and chloride than 8.49E-06, 8.86E-06, and 1.69E-05 as obtained from HCl etched, NaOH, and H2O activated surfaces, respectively.

Palladium chloride catalyzed photochemical Heck reaction

2013 ◽  
Vol 91 (5) ◽  
pp. 348-351 ◽  
Author(s):  
Suresh B. Waghmode ◽  
Sudhir S. Arbuj ◽  
Bina N. Wani ◽  
C.S. Gopinath
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Aryl Halides ◽  
Palladium Chloride ◽  
Carbon Bond ◽  
Excellent Yield ◽  
Carbon Carbon Bond ◽  
Uv Visible

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

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