Reactions of Palladium Chloride with Amino Spirocyclic Cyclotriphosphazenes: Isolation and Crystal Structures of Novel Mono- and Bimetallic Complexes Formed by the Hydrolysis of a .lambda.5-Diazaphospholane Ring

1994 ◽  
Vol 33 (14) ◽  
pp. 3085-3090 ◽  
Author(s):  
A. Chandrasekaran ◽  
S. S. Krishnamurthy ◽  
M. Nethaji
Keyword(s):  
Crystal Structures ◽  
Palladium Chloride ◽  
Bimetallic Complexes ◽  
Hydrolysis Of

Synthesen und Strukturen von 2,5-Bis(2-arylvinyl)-1,4-benzochinonen und deren photochemisches Verhalten im Kristall / Syntheses and Crystal Structures of 2,5-Bis(2-arylvinyl)-1,4-benzoquinones and their Photochemical Reactivity in the Crystalline State

1993 ◽  
Vol 48 (10) ◽  
pp. 1411-1418 ◽  
Author(s):  
Hermann Irngartinger ◽  
Jochen Lichtenthäler ◽  
Dieter Fenske ◽  
Gerhard Baum
Keyword(s):  
Crystal Structures ◽  
Anodic Oxidation ◽  
Crystalline State ◽  
Double Bonds ◽  
Resonance Structures ◽  
Photochemical Reactivity ◽  
X Ray ◽  
Bond Lengths ◽  
Intermolecular Distances ◽  
Hydrolysis Of

The 2,5-bis(2-arylvinyl)-1,4-benzoquinones 1a-1e are formed from hydrolysis of their corresponding ketals 5 which are generated by anodic oxidation of the corresponding 1,4-dimethoxybenzene derivatives 4. The crystal structures of the quinone compounds 1a, 1d and 1e have been determined by X-ray analyses. The bond lengths of the quinone system are influenced by polar resonance structures. An α-type packing mode is observed for the three crystal structures of compounds 1. The vinylic double bonds have short intermolecular distances (1a: 4.417(5), 1d: 3.653(2), 1e: 4.224(5) Å). Only the crystals of 1d with the shortest contacts are photoreactive

Preparations, IR spectra and crystal structures of cyano-bridged bimetallic complexes of zinc(II) and cadmium(II) with tetracyanopalladate(II)

2007 ◽  
Vol 60 (19) ◽  
pp. 2035-2044 ◽  
Author(s):  
Ahmet Karadağ ◽  
Ahmet Bulut ◽  
Ayşegül Şenocak ◽  
İbrahim Uçar ◽  
Orhan Büyükgüngör
Keyword(s):  
Ir Spectra ◽  
Crystal Structures ◽  
Bimetallic Complexes

scholarly journals Structure of lipoprotein lipase in complex with GPIHBP1

2019 ◽  
Vol 116 (21) ◽  
pp. 10360-10365 ◽  
Author(s):  
Rishi Arora ◽  
Amitabh V. Nimonkar ◽  
Daniel Baird ◽  
Chunhua Wang ◽  
Chun-Hao Chiu ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Lipoprotein Lipase ◽  
Structural Information ◽  
Density Lipoprotein ◽  
Lipid Binding ◽  
Structural Basis ◽  
Maturation Factor ◽  
Lipase Maturation Factor 1 ◽  
Hydrolysis Of

Lipoprotein lipase (LPL) plays a central role in triglyceride (TG) metabolism. By catalyzing the hydrolysis of TGs present in TG-rich lipoproteins (TRLs), LPL facilitates TG utilization and regulates circulating TG and TRL concentrations. Until very recently, structural information for LPL was limited to homology models, presumably due to the propensity of LPL to unfold and aggregate. By coexpressing LPL with a soluble variant of its accessory protein glycosylphosphatidylinositol-anchored high-density lipoprotein binding protein 1 (GPIHBP1) and with its chaperone protein lipase maturation factor 1 (LMF1), we obtained a stable and homogenous LPL/GPIHBP1 complex that was suitable for structure determination. We report here X-ray crystal structures of human LPL in complex with human GPIHBP1 at 2.5–3.0 Å resolution, including a structure with a novel inhibitor bound to LPL. Binding of the inhibitor resulted in ordering of the LPL lid and lipid-binding regions and thus enabled determination of the first crystal structure of LPL that includes these important regions of the protein. It was assumed for many years that LPL was only active as a homodimer. The structures and additional biochemical data reported here are consistent with a new report that LPL, in complex with GPIHBP1, can be active as a monomeric 1:1 complex. The crystal structures illuminate the structural basis for LPL-mediated TRL lipolysis as well as LPL stabilization and transport by GPIHBP1.

Bimetallic complexes containing copper. The crystal structures of (tmed)CuMo(CO)3(.eta.5-C5H5) and [(C6H5)3P]3CuV(CO)6

1985 ◽  
Vol 4 (12) ◽  
pp. 2201-2206 ◽  
Author(s):  
Gerald. Doyle ◽  
Kenneth A. Eriksen ◽  
Donna. Van Engen
Keyword(s):  
Crystal Structures ◽  
Bimetallic Complexes

Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N′,N′2-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)

Polyhedron ◽  
2009 ◽  
Vol 28 (12) ◽  
pp. 2397-2402 ◽  
Author(s):  
Tamara R. Todorović ◽  
Urszula Rychlewska ◽  
Beata Warżajtis ◽  
Dušanka D. Radanović ◽  
Nenad R. Filipović ◽  
...  
Keyword(s):  
Antimicrobial Activity ◽  
Crystal Structures ◽  
Bimetallic Complexes

Synthesis and hydrolysis of a fluorosilyl-t-butylaminodichloroalane. Crystal structures of the cyclic compounds [(Me3SiNMe)2SiNCMe3]2 and (Me3CNHAlCl2)2

1983 ◽  
Vol 251 (3) ◽  
pp. 281-287 ◽  
Author(s):  
William Clegg ◽  
Martin Haase ◽  
Uwe Klingebiel ◽  
Jutta Neemann ◽  
George M. Sheldrick
Keyword(s):  
Crystal Structures ◽  
Cyclic Compounds ◽  
Hydrolysis Of

Die Kristallstruktur des Nitridotetrachloromolybdat(VI), [(C6H5)4As] [MoNCl4], und die Hydrolyse zum isotypen Oxotetrachloromolybdat(V), [(C6H6)4As] [MoOCl4] / The Crystal Structure of the Nitrido Tetrachloro Molybdate(VI), [(C6H5)4As][MoNCl4], and the Hydrolysis to the Isotypic Oxo Tetrachloro Molybdate(V), [(C6H5)4As][MoOCl4]

1977 ◽  
Vol 32 (12) ◽  
pp. 1361-1364 ◽  
Author(s):  
Brigitte Knopp ◽  
Klaus-Peter Lörcher ◽  
Joachim Strähle
Keyword(s):  
Crystal Structure ◽  
Crystal Structures ◽  
Partial Hydrolysis ◽  
Space Group ◽  
Hydrolysis Of

The partial hydrolysis of AsPh4[MoNCl4] (AsPh4 = [(C6H5)4As]) leads to AsPh4[MoOCl4]. Both salts crystallize isotypic in the tetragonal space group P 4/n with Z = 2. The crystal structures are built up by AsPh4 cations and square pyramidal [MoXCl4] anions with the symmetry C4v. The Mo—N distance of 166 pm and the slightly longer Mo-O distance of 171 pm indicate strong π-bonding.

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