Hydrogen isotope exchange in methyl-quinones

1968 ◽  
pp. 52 ◽  
Author(s):  
V. M. Clark ◽  
D. W. Hutchinson ◽  
R. G. Wilson
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Hydrogen Isotope Exchange

scholarly journals Are rate and selectivity correlated in iridium-catalysed hydrogen isotope exchange reactions?

2021 ◽  
Author(s):  
Daria S. Timofeeva ◽  
David M Lindsay ◽  
W. J. Kerr ◽  
David James Nelson
Keyword(s):  
Functional Groups ◽  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Reaction Rate ◽  
Exchange Reactions ◽  
Reaction Selectivity ◽  
Hydrogen Isotope Exchange ◽  
The Relationship

Herein we examine the relationship between reaction rate and reaction selectivity in iridium-catalysed hydrogen isotope exchange (HIE) reactions directed by Lewis basic functional groups. We have recently develped a directing...

Hydrogen isotope exchange between D2 and H2O catalyzed by platinum plate

1989 ◽  
Vol 67 (5) ◽  
pp. 857-861 ◽  
Author(s):  
Shin-Ichi Miyamoto ◽  
Tetsuo Sakka ◽  
Matae Iwasaki
Keyword(s):  
Kinetic Model ◽  
Exchange Reaction ◽  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Reaction Rate ◽  
Hydrogen Adsorption ◽  
Platinum Catalyst ◽  
Isotope Exchange Reaction ◽  
Hydrogen Isotope Exchange ◽  
Supported Platinum

The reaction rate of hydrogen isotope exchange between D2 and H2O catalyzed by platinum plate is studied. The exchange reaction is described with the kinetic model which is the modification of that for the exchange reaction catalyzed by alumina-supported platinum catalyst. For the comparison of experimental results with this model relative amount of the number of sites for hydrogen adsorption was estimated from the initial rate of hydrogen isotope exchange between H2 and D2 on the same surface. The results show that the kinetic model is applicable for the plate catalyst if the number of the sites for hydrogen absorption, which is very sensitive to the surface state of the catalyst, was estimated not from the macroscopic surface area but from our scheme. Keywords: hydrogen isotope exchange reaction, platinum plate as catalyst.

Two-film effects on the kinetics of hydrogen isotope exchange between CHCl3 and D2O in two liquid phase system

1993 ◽  
Vol 25 (5) ◽  
pp. 363-374
Author(s):  
Matae Iwasaki ◽  
Tetsuo Sakka ◽  
Shigeyuki Ohashi ◽  
Yoshikazu Miyake ◽  
Hiroshi Matsushita
Keyword(s):  
Liquid Phase ◽  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Phase System ◽  
Hydrogen Isotope Exchange ◽  
Kinetics Of

scholarly journals Highly active iridium(i) complexes for catalytic hydrogen isotope exchange

2008 ◽  
pp. 1115 ◽  
Author(s):  
Jack A. Brown ◽  
Stephanie Irvine ◽  
Alan R. Kennedy ◽  
William J. Kerr ◽  
Shalini Andersson ◽  
...  
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Hydrogen Isotope Exchange ◽  
Highly Active ◽  
Catalytic Hydrogen

Ortho-Deuteration of Aromatic Aldehydes via a Transient Directing Group-Enabled Pd-Catalyzed Hydrogen Isotope Exchange

2021 ◽  
Vol 86 (19) ◽  
pp. 13350-13359
Author(s):  
Junhua Kong ◽  
Zhi-Jiang Jiang ◽  
Jiayuan Xu ◽  
Yan Li ◽  
Hong Cao ◽  
...  
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Aromatic Aldehydes ◽  
Hydrogen Isotope Exchange ◽  
Directing Group

scholarly journals Hydrogen isotope exchange in tungsten during annealing in hydrogen atmosphere

2019 ◽  
Vol 59 (2) ◽  
pp. 026016 ◽  
Author(s):  
T. Ahlgren ◽  
P. Jalkanen ◽  
K. Mizohata ◽  
V. Tuboltsev ◽  
J. Räisänen ◽  
...  
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Hydrogen Atmosphere ◽  
Hydrogen Isotope Exchange

On the mechanisms of acid-catalyzed enolization and hydrogen isotope exchange of cyclic ketones

1977 ◽  
Vol 55 (1) ◽  
pp. 173-176 ◽  
Author(s):  
Nick Henry Werstiuk ◽  
Sujit Banerjee
Keyword(s):  
General Theory ◽  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Rate Data ◽  
Cyclic Ketones ◽  
Proton Pair ◽  
Hydrogen Isotope Exchange ◽  
Bicyclic Ketones ◽  
Acid Catalyzed ◽  
Reactivity Order

The acid-catalyzed hydrogen isotope exchange of norcamphor 1 in DOAc–DCl–D2O is shown to follow the general theory (4) for exchange of a diastereotopic proton pair α to a carbonyl group. That is, the less reactive proton undergoes exchange via two channels. Through an analysis of a combination of the rate data for acid-catalyzed bromination and the pKBH+ values for a series of cyclic and bicyclic ketones, we establish that the reactivity order in the former is controlled by ketone basicity and not, as has been suggested previously, by angle strain developed in a very enol-like transition state.

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