Fabrication of three dimensional CeO2 hierarchical structures: Precursor template synthesis, formation mechanism and properties

CrystEngComm ◽  
2011 ◽  
Vol 13 (7) ◽  
pp. 2418 ◽  
Author(s):  
Jingjing Wei ◽  
Zhijie Yang ◽  
Yanzhao Yang
2015 ◽  
Vol 2 (6) ◽  
pp. 567-575 ◽  
Author(s):  
Yong-Xia Zhao ◽  
Zhi-Wen Nie ◽  
Meng-Meng Shi ◽  
Cheng-Hui Zeng ◽  
Yuan Li ◽  
...  

Novel three-dimensional (3D) ceria hierarchical structures have been prepared via a thermolysis of the corresponding porous coordination polymer precursors.


CrystEngComm ◽  
2010 ◽  
Vol 12 (7) ◽  
pp. 2166 ◽  
Author(s):  
Lingling Xu ◽  
Zeming Li ◽  
Qinghai Cai ◽  
Hongxia Wang ◽  
Hong Gao ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Chaojian Chen ◽  
Manjesh Kumar Singh ◽  
Katrin Wunderlich ◽  
Sean Harvey ◽  
Colette J. Whitfield ◽  
...  

AbstractThe creation of synthetic polymer nanoobjects with well-defined hierarchical structures is important for a wide range of applications such as nanomaterial synthesis, catalysis, and therapeutics. Inspired by the programmability and precise three-dimensional architectures of biomolecules, here we demonstrate the strategy of fabricating controlled hierarchical structures through self-assembly of folded synthetic polymers. Linear poly(2-hydroxyethyl methacrylate) of different lengths are folded into cyclic polymers and their self-assembly into hierarchical structures is elucidated by various experimental techniques and molecular dynamics simulations. Based on their structural similarity, macrocyclic brush polymers with amphiphilic block side chains are synthesized, which can self-assemble into wormlike and higher-ordered structures. Our work points out the vital role of polymer folding in macromolecular self-assembly and establishes a versatile approach for constructing biomimetic hierarchical assemblies.


RSC Advances ◽  
2019 ◽  
Vol 9 (17) ◽  
pp. 9584-9593 ◽  
Author(s):  
Le Lam Son ◽  
Nguyen Duc Cuong ◽  
Tran Thi Van Thi ◽  
Le Trung Hieu ◽  
Do Dang Trung ◽  
...  

Biopolymer template synthesis has attracted extensive interest for fabricating highly porous metal oxide nanostructures.


2011 ◽  
Vol 21 (40) ◽  
pp. 16223 ◽  
Author(s):  
Yi Shi ◽  
Xiang Li ◽  
Junkai Hu ◽  
Jinhua Lu ◽  
Yuchun Ma ◽  
...  

CrystEngComm ◽  
2013 ◽  
Vol 15 (5) ◽  
pp. 1007-1014 ◽  
Author(s):  
Qianqian Shen ◽  
Jinbo Xue ◽  
Jian Liu ◽  
Husheng Jia ◽  
Xuguang Liu ◽  
...  

Author(s):  
Chenyu Zhao ◽  
Xun Liu

Abstract Three-dimensional computational fluid dynamics models are developed to understand physical principles of self-reacting friction stir welding process. A novel approach of predicting the weld microstructure based on plastic strain distribution at cross-section behind the tool is proposed and verified with experimental results. Limitations and credibility of shear stress and velocity tool/workpiece boundary condition are evaluated from the perspective of the weld formation mechanism. The importance of the shear layer and its sticking/sliding transition state in weld formation mechanism is emphasized. From modeling perspective, shear stress boundary, which only represents a sliding condition, neglects the movement and effects of this shear layer. When shear layer is formed, due to the velocity discontinuity which could not be captured in fluid model, velocity boundary condition, which represents an averaging effect of sticking/sliding transition between tool and shear layer, is needed.


2002 ◽  
Vol 166 (2) ◽  
pp. 369-374 ◽  
Author(s):  
Yongnan Zhao ◽  
Jing Ju ◽  
Xiangming Chen ◽  
Xiuhong Li ◽  
Yong Wang ◽  
...  

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