Guiding the nitrogen nucleophile to the middle: palladium-catalyzed decarboxylative cyclopropanation of 2-alkylidenetrimethylene carbonates with isocyanates

2011 ◽  
Vol 47 (11) ◽  
pp. 3057 ◽  
Author(s):  
Ryo Shintani ◽  
Kohei Moriya ◽  
Tamio Hayashi
Keyword(s):  
Nitrogen Nucleophile ◽  
Palladium Catalyzed

Palladium-catalyzed amination of 2,3,3-trifluoroallyl esters: synthesis of trifluoromethylenamines via an intramolecular fluorine shift and CF3 group construction

2015 ◽  
Vol 51 (31) ◽  
pp. 6761-6764 ◽  
Author(s):  
Kazuki Isa ◽  
Maki Minakawa ◽  
Motoi Kawatsura
Keyword(s):  
Fluorine Atom ◽  
Nitrogen Nucleophile ◽  
Palladium Catalyzed ◽  
Group Construction

The palladium-catalyzed reaction of 2,3,3-trifluoroallyl esters with amines afforded trifluoromethylenamines, which were formed by the addition of a nitrogen nucleophile at the C-2 position and the fluorine atom shift from the C-2 to C-3 position.

Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Aryl Iodide ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

2020 ◽  
Vol 7 (6) ◽  
pp. 885-889 ◽  
Author(s):  
Xinxin Qi ◽  
Zhi-Peng Bao ◽  
Xiao-Feng Wu
Keyword(s):  
Sulfonyl Chlorides ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

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