Monitoring adsorption-induced switching by 129Xe NMR spectroscopy in a new metal–organic framework Ni2(2,6-ndc)2(dabco)

2010 ◽  
Vol 12 (37) ◽  
pp. 11778 ◽  
Author(s):  
Nicole Klein ◽  
Christin Herzog ◽  
Michal Sabo ◽  
Irena Senkovska ◽  
Jürgen Getzschmann ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Metal Organic Framework ◽  
129Xe Nmr ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Arene guest selectivity and pore flexibility in a metal–organic framework with semi-fluorinated channel walls

2017 ◽  
Vol 375 (2084) ◽  
pp. 20160031 ◽  
Author(s):  
Rebecca Smith ◽  
Iñigo J. Vitórica-Yrezábal ◽  
Adrian Hill ◽  
Lee Brammer
Keyword(s):  
Nmr Spectroscopy ◽  
Metal Organic Framework ◽  
Magic Angle Spinning ◽  
Nitrogen Atmosphere ◽  
Magic Angle ◽  
Ambient Conditions ◽  
Solid State Transformation ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework (MOF) with one-dimensional channels of approximately hexagonal cross-section [Ag 2 (O 2 CCF 2 CF 2 CO 2 )(TMP)] 1 (TMP =2,3,5,6-tetramethylpyrazine) has been synthesized with MeOH filling the channels in its as-synthesized form as [Ag 2 (O 2 CCF 2 CF 2 CO 2 )(TMP)]· n (MeOH) 1-MeOH ( n  = 1.625 by X-ray crystallography). The two types of ligand connect columns of Ag(I) centres in an alternating manner, both around the channels and along their length, leading to an alternating arrangement of hydrocarbon (C–H) and fluorocarbon (C–F) groups lining the channel walls, with the former groups projecting further into the channel than the latter. MeOH solvent in the channels can be exchanged for a variety of arene guests, ranging from xylenes to tetrafluorobenzene, as confirmed by gas chromatography, 1 H nuclear magnetic resonance (NMR) spectroscopy, thermogravimetric analysis and 13 C cross-polarization magic angle spinning NMR spectroscopy. Alkane and perfluoroalkane guests, however, do not enter the channels. Although exhibiting some stability under a nitrogen atmosphere, sufficient to enable crystal structure determination, the evacuated MOF 1 is unstable for periods of more than minutes under ambient conditions or upon heating, whereupon it undergoes an irreversible solid-state transformation to a non-porous polymorph 2 , which comprises Ag 2 (O 2 CCF 2 CF 2 CO 2 ) coordination layers that are pillared by TMP ligands. This transformation has been followed in situ by powder X-ray diffraction and shown to proceed via a crystalline intermediate. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

scholarly journals Uncovering the Local Magnesium Environment in the Metal–Organic Framework Mg2(dobpdc) Using 25Mg NMR Spectroscopy

2017 ◽  
Vol 121 (36) ◽  
pp. 19938-19945 ◽  
Author(s):  
Jun Xu ◽  
E. S. Merijn Blaakmeer ◽  
Andrew S. Lipton ◽  
Thomas M. McDonald ◽  
Yifei Michelle Liu ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Solid-State NMR Spectroscopy of Metal–Organic Framework Compounds (MOFs)

Materials ◽  
2012 ◽  
Vol 5 (12) ◽  
pp. 2537-2572 ◽  
Author(s):  
Herbert Hoffmann ◽  
Marta Debowski ◽  
Philipp Müller ◽  
Silvia Paasch ◽  
Irena Senkovska ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Metal Organic Framework ◽  
Solid State Nmr Spectroscopy ◽  
Metal Organic ◽  
Framework Compounds ◽  
Organic Framework

scholarly journals NMR Spectroscopy Reveals Adsorbate Binding Sites in the Metal–Organic Framework UiO-66(Zr)

2018 ◽  
Vol 122 (15) ◽  
pp. 8295-8305 ◽  
Author(s):  
Aditya Nandy ◽  
Alexander C. Forse ◽  
Velencia J. Witherspoon ◽  
Jeffrey A. Reimer
Keyword(s):  
Nmr Spectroscopy ◽  
Binding Sites ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Mobility of Aromatic Guests and Isobutane in ZIF-8 Metal–Organic Framework Studied by 2H Solid State NMR Spectroscopy

2019 ◽  
Vol 123 (22) ◽  
pp. 13765-13774 ◽  
Author(s):  
Alexander E. Khudozhitkov ◽  
Sergei S. Arzumanov ◽  
Daniil I. Kolokolov ◽  
Alexander G. Stepanov
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Metal Organic Framework ◽  
Solid State Nmr Spectroscopy ◽  
Metal Organic ◽  
Organic Framework

Alkyldiamine bis(selenocyanato)cadmium(II) complexes: Synthesis, 113Cd, 77Se, 15N and 13C NMR spectroscopy and X-ray structure of a 2D metal–organic framework

Polyhedron ◽  
2011 ◽  
Vol 30 (7) ◽  
pp. 1262-1266 ◽  
Author(s):  
Mohammed Fettouhi ◽  
Bassem A. Al-Maythalony ◽  
M. Nasiruzzaman Shaikh ◽  
Mohammed I.M. Wazeer ◽  
Anvarhusein A. Isab
Keyword(s):  
Nmr Spectroscopy ◽  
13C Nmr ◽  
Metal Organic Framework ◽  
13C Nmr Spectroscopy ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

High-Pressure in Situ129Xe NMR Spectroscopy and Computer Simulations of Breathing Transitions in the Metal–Organic Framework Ni2(2,6-ndc)2(dabco) (DUT-8(Ni))

2011 ◽  
Vol 133 (22) ◽  
pp. 8681-8690 ◽  
Author(s):  
Herbert C. Hoffmann ◽  
Bassem Assfour ◽  
Fanny Epperlein ◽  
Nicole Klein ◽  
Silvia Paasch ◽  
...  
Keyword(s):  
High Pressure ◽  
Nmr Spectroscopy ◽  
Computer Simulations ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
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