High-Pressure in Situ129Xe NMR Spectroscopy and Computer Simulations of Breathing Transitions in the Metal–Organic Framework Ni2(2,6-ndc)2(dabco) (DUT-8(Ni))

2011 ◽  
Vol 133 (22) ◽  
pp. 8681-8690 ◽  
Author(s):  
Herbert C. Hoffmann ◽  
Bassem Assfour ◽  
Fanny Epperlein ◽  
Nicole Klein ◽  
Silvia Paasch ◽  
...  
Keyword(s):  
High Pressure ◽  
Nmr Spectroscopy ◽  
Computer Simulations ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Peculiarities of high-pressure hydrogen adsorption on Pt catalyzed Cu-BTC metal–organic framework

2021 ◽  
Vol 23 (7) ◽  
pp. 4277-4286
Author(s):  
S. V. Chuvikov ◽  
E. A. Berdonosova ◽  
A. Krautsou ◽  
J. V. Kostina ◽  
V. V. Minin ◽  
...  
Keyword(s):  
High Pressure ◽  
High Pressures ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Pt Catalyst ◽  
Metal Organic ◽  
Pt Catalyzed ◽  
Pressure Hydrogen ◽  
Organic Framework

Pt-Catalyst plays a key role in hydrogen adsorption by Cu-BTC at high pressures.

scholarly journals Arene guest selectivity and pore flexibility in a metal–organic framework with semi-fluorinated channel walls

2017 ◽  
Vol 375 (2084) ◽  
pp. 20160031 ◽  
Author(s):  
Rebecca Smith ◽  
Iñigo J. Vitórica-Yrezábal ◽  
Adrian Hill ◽  
Lee Brammer
Keyword(s):  
Nmr Spectroscopy ◽  
Metal Organic Framework ◽  
Magic Angle Spinning ◽  
Nitrogen Atmosphere ◽  
Magic Angle ◽  
Ambient Conditions ◽  
Solid State Transformation ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework (MOF) with one-dimensional channels of approximately hexagonal cross-section [Ag 2 (O 2 CCF 2 CF 2 CO 2 )(TMP)] 1 (TMP =2,3,5,6-tetramethylpyrazine) has been synthesized with MeOH filling the channels in its as-synthesized form as [Ag 2 (O 2 CCF 2 CF 2 CO 2 )(TMP)]· n (MeOH) 1-MeOH ( n  = 1.625 by X-ray crystallography). The two types of ligand connect columns of Ag(I) centres in an alternating manner, both around the channels and along their length, leading to an alternating arrangement of hydrocarbon (C–H) and fluorocarbon (C–F) groups lining the channel walls, with the former groups projecting further into the channel than the latter. MeOH solvent in the channels can be exchanged for a variety of arene guests, ranging from xylenes to tetrafluorobenzene, as confirmed by gas chromatography, 1 H nuclear magnetic resonance (NMR) spectroscopy, thermogravimetric analysis and 13 C cross-polarization magic angle spinning NMR spectroscopy. Alkane and perfluoroalkane guests, however, do not enter the channels. Although exhibiting some stability under a nitrogen atmosphere, sufficient to enable crystal structure determination, the evacuated MOF 1 is unstable for periods of more than minutes under ambient conditions or upon heating, whereupon it undergoes an irreversible solid-state transformation to a non-porous polymorph 2 , which comprises Ag 2 (O 2 CCF 2 CF 2 CO 2 ) coordination layers that are pillared by TMP ligands. This transformation has been followed in situ by powder X-ray diffraction and shown to proceed via a crystalline intermediate. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

High pressure studies of metal organic framework materials

2012 ◽  
Vol 9 (1/2) ◽  
pp. 18 ◽  
Author(s):  
Stephen A. Moggach ◽  
Alexander J. Graham ◽  
Anna Muszkiewicz ◽  
Carole A. Morrison
Keyword(s):  
High Pressure ◽  
Metal Organic Framework ◽  
Framework Materials ◽  
High Pressure Studies ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Formulation of Metal–Organic Framework Inks for the 3D Printing of Robust Microporous Solids toward High-Pressure Gas Storage and Separation

2020 ◽  
Vol 12 (9) ◽  
pp. 10983-10992 ◽  
Author(s):  
Jérémy Dhainaut ◽  
Mickaële Bonneau ◽  
Ryota Ueoka ◽  
Kazuyoshi Kanamori ◽  
Shuhei Furukawa
Keyword(s):  
High Pressure ◽  
3D Printing ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
Metal Organic ◽  
Microporous Solids ◽  
Organic Framework

scholarly journals Uncovering the Local Magnesium Environment in the Metal–Organic Framework Mg2(dobpdc) Using 25Mg NMR Spectroscopy

2017 ◽  
Vol 121 (36) ◽  
pp. 19938-19945 ◽  
Author(s):  
Jun Xu ◽  
E. S. Merijn Blaakmeer ◽  
Andrew S. Lipton ◽  
Thomas M. McDonald ◽  
Yifei Michelle Liu ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Remarkable resilience of the formate cage in a multiferroic metal organic framework material: dimethyl ammonium manganese formate (DMAMnF)

2018 ◽  
Vol 47 (37) ◽  
pp. 12993-13005 ◽  
Author(s):  
Abhishek V. Chitnis ◽  
Himal Bhatt ◽  
Miroslaw Mączka ◽  
Mukul N. Deo ◽  
Nandini Garg
Keyword(s):  
Phase Transition ◽  
High Pressure ◽  
Metal Organic Framework ◽  
Crystal Phase ◽  
Dimethyl Ammonium ◽  
Metal Organic ◽  
Crystal Phase Transition ◽  
Organic Framework

Shrinking of the cavity formed by the MnO6 octahedra and formate linkers, initiates the distortion of the formate network in DMAMnF and results in ordering of the DMA+ cation, leading to a crystal to crystal phase transition at high pressure.

Probing dynamics of carbon dioxide in a metal–organic framework under high pressure by high-resolution solid-state NMR

2020 ◽  
Vol 22 (26) ◽  
pp. 14465-14470
Author(s):  
Munehiro Inukai ◽  
Takuya Kurihara ◽  
Yasuto Noda ◽  
Weiming Jiang ◽  
Kiyonori Takegoshi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Solid State ◽  
High Resolution ◽  
Solid State Nmr ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

We performed high-resolution solid-state NMR analyses for CO2 molecules adsorbed in MOF-74 under high pressure conditions.

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