Nature and role of surface carbonates and bicarbonates in CO oxidation over RuO2

2010 ◽  
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pp. 6367 ◽  
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William F. Schneider
2006 ◽  
Vol 258-260 ◽  
pp. 63-67
Author(s):  
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V.P. Maryevich ◽  
V.A. Shashmurin

Diffusion processes play a dominant part in the macro kinetics of Fe, Ni and Co oxidation by calcium and sodium sulfates. Here, the reaction product forms a compact covering which spatially divides the reagents on the surface in the same way as in the oxidation and sulfidization of metals by oxygen and sulfur. Therefore, it is possible to assume in advance that interaction of metals with calcium and sodium sulfates will be determined not by the actual chemical reaction properly but by the diffusion transport processes.


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