Ionic liquids assisted formation of an oil/water emulsion stabilised by a carbon nanotube/ionic liquid composite layer

2010 ◽  
Vol 12 (11) ◽  
pp. 2535 ◽  
Author(s):  
Lili Gao ◽  
Huayi Yin ◽  
Dihua Wang
RSC Advances ◽  
2016 ◽  
Vol 6 (86) ◽  
pp. 82726-82732 ◽  
Author(s):  
Li Luo ◽  
Zheng Zhou ◽  
Ye Ren ◽  
Guang-Xin Chen ◽  
Qifang Li

A type of skin-core structured hybrid with a multi-walled carbon nanotube (MWCNT) center was synthesized by in situ free-radical polymerization of vinyl-benzyl ionic liquid and divinylbenzene on the outer surface of MWCNTs.


AIChE Journal ◽  
2011 ◽  
Vol 58 (4) ◽  
pp. 1203-1211 ◽  
Author(s):  
Yangyang Jiang ◽  
Chen Guo ◽  
Hongshuai Gao ◽  
Hansong Xia ◽  
Iram Mahmood ◽  
...  

2017 ◽  
Author(s):  
Jose A. Pomposo

Understanding the miscibility behavior of ionic liquid (IL) / monomer, IL / polymer and IL / nanoparticle mixtures is critical for the use of ILs as green solvents in polymerization processes, and to rationalize recent observations concerning the superior solubility of some proteins in ILs when compared to standard solvents. In this work, the most relevant results obtained in terms of a three-component Flory-Huggins theory concerning the “Extra Solvent Power, ESP” of ILs when compared to traditional non-ionic solvents for monomeric solutes (case I), linear polymers (case II) and globular nanoparticles (case III) are presented. Moreover, useful ESP maps are drawn for the first time for IL mixtures corresponding to case I, II and III. Finally, a potential pathway to improve the miscibility of non-ionic polymers in ILs is also proposed.


2020 ◽  
Author(s):  
Swati Arora ◽  
Julisa Rozon ◽  
Jennifer Laaser

<div>In this work, we investigate the dynamics of ion motion in “doubly-polymerized” ionic liquids (DPILs) in which both charged species of an ionic liquid are covalently linked to the same polymer chains. Broadband dielectric spectroscopy is used to characterize these materials over a broad frequency and temperature range, and their behavior is compared to that of conventional “singly-polymerized” ionic liquids (SPILs) in which only one of the charged species is attached to the polymer chains. Polymerization of the DPIL decreases the bulk ionic conductivity by four orders of magnitude relative to both SPILs. The timescales for local ionic rearrangement are similarly found to be approximately four orders of magnitude slower in the DPILs than in the SPILs, and the DPILs also have a lower static dielectric constant. These results suggest that copolymerization of the ionic monomers affects ion motion on both the bulk and the local scales, with ion pairs serving to form strong physical crosslinks between the polymer chains. This study provides quantitative insight into the energetics and timescales of ion motion that drive the phenomenon of “ion locking” currently under investigation for new classes of organic electronics.</div>


1998 ◽  
Author(s):  
S. Venkatesh ◽  
C. Watson ◽  
C. D. Wolbach ◽  
L. R. Waterland

2019 ◽  
Vol 16 (7) ◽  
pp. 550-555
Author(s):  
Dinesh K. Jangid ◽  
Keshav L. Ameta ◽  
Surbhi Dhadda ◽  
Anjali Guleria ◽  
Prakash G. Goswami ◽  
...  

Ionic Liquid assisted efficient synthesis of some 2-aminobenzenethiols has been reported using three different Ionic Liquids (ILs) namely methylimidazolium tetrafluoroborate [MIM]+[BF4]−, methylimidazolium chloride [MIM]+[Cl]− and methylimidazolium nitrate [MIM]+[NO3]−. A comparative study has been carried out for the synthesis of target molecules in the presence and absence of IL, leading to conclusion that maximum yield has been observed with [MIM]+[BF4]−.


Sign in / Sign up

Export Citation Format

Share Document