Synthesis, structure and luminescent properties of coordination polymers with 1,2-benzenedicarboxylic acid and a series of flexible dicarboxylate ligands

CrystEngComm ◽  
2010 ◽  
Vol 12 (3) ◽  
pp. 762-773 ◽  
Author(s):  
Zhuo Wang ◽  
Yong-Heng Xing ◽  
Chun-Guang Wang ◽  
Li-Xian Sun ◽  
Jian Zhang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Luminescent Properties ◽  
Benzenedicarboxylic Acid

scholarly journals Effect of Charge on the Structures of Zn(II) Coordination Polymers with Triazole-carboxylate Ligands: Syntheses, Structures, and Luminescent Properties

Crystals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 312 ◽  
Author(s):  
Shaobin Miao ◽  
Xiaojuan Sun ◽  
Kexin Wang ◽  
Chunying Xu ◽  
Zhaohao Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Positive Charge ◽  
Luminescent Properties ◽  
Chain Structure ◽  
Double Layers ◽  
Carboxylate Ligands ◽  
Benzenedicarboxylic Acid ◽  
1D Chain ◽  
3D Framework ◽  
State Luminescence

Three new Zn(II) coordination polymers, {[Zn(L1)2(H2O)2]·4H2O}n (1), {[Zn(L2)(H2O)2]·0.5H2O}n (2), and {[Zn1.5(L1)(o-bdc)(H2O)]·0.5H2O}n (3) (HL1 = 3,5-di(1,2,4-triazol-1-yl)benzoic acid, H2L2 = 5-(triazol-1-yl)isophthalic acid, o-H2bdc = 1,2-benzenedicarboxylic acid), were successfully synthesized and characterized. Compound 1 exhibits 1D chain structure containing [Zn(L1)2] unit. Compound 2 shows a 2D plane with the ratio of Zn:L2 was 1:1 since L2 can match the positive charge of Zn(II). When L1 and o-bdc2– were presented together, Zn(II) centers are linked by L1 to form 2D double layers, then o-bdc2– further connected the adjacent layers to generate final 3D framework of 3. The ligand charges may play key roles in tuning the frameworks of compounds 1–3. The solid state luminescence of compounds 1–3 and all ligands have been investigated here.

Syntheses, X-ray structures, gas adsorption and luminescent properties of three coordination polymers of Zn(ii) dicarboxylates mixed with a linear, neutral, and rigid N,N′-donor ligand

CrystEngComm ◽  
2014 ◽  
Vol 16 (22) ◽  
pp. 4783-4795 ◽  
Author(s):  
Biswajit Bhattacharya ◽  
Debraj Saha ◽  
Dilip Kumar Maity ◽  
Rajdip Dey ◽  
Debajyoti Ghoshal
Keyword(s):  
Coordination Polymers ◽  
Gas Adsorption ◽  
Luminescent Properties ◽  
Donor Ligand ◽  
X Ray
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