Structural diversity and modulation of metal–organic coordination frameworks with a flexible V-shaped dicarboxyl building block

CrystEngComm ◽  
2009 ◽  
Vol 11 (5) ◽  
pp. 855 ◽  
Author(s):  
Xiu-Juan Jiang ◽  
Su-Zhen Zhang ◽  
Jian-Hua Guo ◽  
Xiu-Guang Wang ◽  
Jin-Shan Li ◽  
...  
CrystEngComm ◽  
2016 ◽  
Vol 18 (12) ◽  
pp. 2189-2202 ◽  
Author(s):  
Darpandeep Aulakh ◽  
Anthony P. Nicoletta ◽  
Juby R. Varghese ◽  
Mario Wriedt

A viologen based ligand has been explored as a functional building block to synthesize a series of nine new zwitterionic metal–organic frameworks with this contribution reporting on their structural, thermal and photochromic properties.


2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.


Catalysts ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1441
Author(s):  
Fangyu Ren ◽  
Pengfei Ji

Polymers have become one of the major types of materials that are essential in our daily life. The controlled synthesis of value-added polymers with unique mechanical and chemical properties have attracted broad research interest. Metal–organic framework (MOF) is a class of porous material with immense structural diversity which offers unique advantages for catalyzing polymerization and oligomerization reactions including the uniformity of the catalytic active site, and the templating effect of the nano-sized channels. We summarized in this review the important recent progress in the field of MOF-catalyzed and MOF-templated polymerizations, to reveal the chemical principle and structural aspects of these systems and hope to inspire the future design of novel polymerization systems with improved activity and specificity.


2018 ◽  
Vol 54 (22) ◽  
pp. 2735-2738 ◽  
Author(s):  
Andrey A. Bezrukov ◽  
Karl W. Törnroos ◽  
Erwan Le Roux ◽  
Pascal D. C. Dietzel

A dimeric Zr12 oxo cluster was used as new molecular building block in construction of metal–organic frameworks utilizing the precursor approach.


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