Towards a general solid phase approach for the iterative synthesis of conjugated oligomers using a germanium based linker - first solid phase synthesis of an oligo-(triarylamine)

2007 ◽  
Vol 5 (11) ◽  
pp. 1752-1763 ◽  
Author(s):  
David J. Turner ◽  
Rémi Anémian ◽  
Philip R. Mackie ◽  
Domenico C. Cupertino ◽  
Stephen G. Yeates ◽  
...  
Keyword(s):  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Conjugated Oligomers ◽  
Phase Synthesis ◽  
Phase Approach ◽  
Iterative Synthesis

scholarly journals A solid-phase approach for the synthesis of α-aminoboronic acid peptides

RSC Advances ◽  
2018 ◽  
Vol 8 (6) ◽  
pp. 3343-3347 ◽  
Author(s):  
Blake E. Daniels ◽  
Craig E. Stivala
Keyword(s):  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Phase Synthesis ◽  
Phase Approach ◽  
Polystyrene Resin

A solid-phase synthesis of α-aminoboronic acid peptides using a 1-glycerol polystyrene resin is described.

scholarly journals Solid-phase synthesis provides a modular, lysine-based platform for fluorescent discrimination of nitroxyl and biological thiols

2015 ◽  
Vol 6 (7) ◽  
pp. 4131-4140 ◽  
Author(s):  
Andrei Loas ◽  
Robert J. Radford ◽  
Alexandria Deliz Liang ◽  
Stephen J. Lippard
Keyword(s):  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Live Cells ◽  
Phase Synthesis ◽  
Phase Approach

A synthetically facile solid-phase approach yields fluorescent Cu(ii)-based lysine conjugates which selectively detect nitroxyl and thiols in live cells.

A Novel Strategy for the Solid Phase Synthesis of Ultra Pure Organic Semiconductors

2003 ◽  
Vol 771 ◽  
Author(s):  
D. Turner ◽  
A. Spivey ◽  
D. Cupertino ◽  
P. Mackie ◽  
R. Anemian ◽  
...  
Keyword(s):  
Organic Semiconductors ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Cross Coupling ◽  
Phase Synthesis ◽  
Synthetic Strategy ◽  
Novel Strategy ◽  
Key Steps ◽  
Iterative Synthesis

AbstractA new solid phase synthetic strategy for the production of organic semiconductors has been developed. The strategy uses a germanium-based linker and Suzuki-type cross-coupling protocols and has been demonstrated for the iterative synthesis of both a regio-regular oligo-3-alkyl-thiophene and an oligoarylamine. The process also incorporates a novel “doublecoupling” after each iteration which minimizes deletion sequences. The key steps exploits the susceptibility of α-silyl- or α-silyloxy- but not germyl-substituted derivatives toward nucleophilic ipso-protodemetalation.

Sign in / Sign up

Export Citation Format

Share Document