Direct solvothermal growth, crystal structures, and optical properties of one-dimensional lanthanide selenidoarsenate(v) polymers [Ln(dien)2(µ3-AsSe4)] (Ln = Nd, Sm): the first example of an AsSe43−anion acting as a ligand to a lanthanide complex

2007 ◽  
pp. 2083-2086 ◽  
Author(s):  
Dingxian Jia ◽  
Aimei Zhu ◽  
Jie Deng ◽  
Yong Zhang ◽  
Jie Dai
Keyword(s):  
Optical Properties ◽  
Crystal Structures ◽  
Lanthanide Complex ◽  
One Dimensional

Notizen: Preparation, Structures and Optical Properties of [H3N(CH2)6NH3]BiX5 (X=I, Cl) and [H3N(CH2)6NH3]SbX5 (X=I, Br)

1998 ◽  
Vol 53 (8) ◽  
pp. 927-932 ◽  
Author(s):  
G. A. Mousdis ◽  
G. C. Papavassiliou ◽  
A. Terzis ◽  
C. P. Raptopoulou
Keyword(s):  
Optical Properties ◽  
Optical Absorption ◽  
Crystal Structures ◽  
Absorption Spectra ◽  
Blue Shift ◽  
Optical Absorption Spectra ◽  
Absorption Bands ◽  
One Dimensional ◽  
Excitonic Absorption

Abstract The preparation, crystal structures and optical absorption spectra of [H3N(CH2)6NH3]BiX5 (X= I, Cl) and [H3N(CH2)6NH3]SbX5 (X =I, Br) are reported. The anions of the compounds consist of MX6-octahedra (M =Bi, Sb) sharing cisvertices in one-dimensional zig-zag chains. Because of their one-dimensional character, a blue shift of the excitonic absorption bands, in com parison to those of higher dim ensionality systems (MX3), is observed.

One-dimensional polymeric iodoplumbate hybrids with lanthanide complex cations: syntheses, crystal structures, and photoelectric and photocatalytic properties

2020 ◽  
Vol 44 (44) ◽  
pp. 19166-19173
Author(s):  
Niannian Chen ◽  
Yan Gao ◽  
Yiming Tian ◽  
Bing Wu ◽  
Dingxian Jia ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Crystal Structures ◽  
Current Density ◽  
Lanthanide Complexes ◽  
Lanthanide Complex ◽  
Photocatalytic Properties ◽  
Photocurrent Response ◽  
One Dimensional ◽  
Response Current

New iodoplumbate hybrids were prepared using lanthanide complexes as SDAs. They exhibit a high photocurrent response, current density and photocatalytic activity in the degradation of CV.

Syntheses, crystal structures and optical properties of two one-dimensional germanophosphates: HRb3Ge2(HPO4)6 and CsGe(HPO4)2(OH)

2018 ◽  
Vol 74 (10) ◽  
pp. 1146-1152
Author(s):  
Jun-Ling Song ◽  
Wen-Xiu Lu ◽  
Tian-Shuo Guo ◽  
Yu-Hua Zhou
Keyword(s):  
Optical Properties ◽  
Alkali Metal ◽  
Crystal Structures ◽  
Absorption Spectra ◽  
Solvothermal Method ◽  
One Dimensional ◽  
Metal Phosphates ◽  
Structural Types ◽  
Nir Absorption ◽  
Potential Applications

Germanophosphates, as a young class of metal phosphates, have been less reported but might possess more diverse structural types and potential applications. Here, two one-dimensional (1D) alkali-metal germanophosphates (GePOs), namely, hydrogen hexakis(μ-hydrogen phosphato)digermaniumtrirubidium, HRb3Ge2(HPO4)6 (1), and caesium bis(μ-hydrogen phosphato)(μ-hydroxido)germanium, CsGe(HPO4)2(OH) (2), have been prepared by the solvothermal method. Compound 1 shows 1D [Ge(HPO4)6]∞ chains along the c axis formed by GeO6 octahedra and PO4 tetrahedra, with Rb+ cations dissociated between the chains. Compound 2 also exhibits 1D [Ge(HPO4)4(OH)2]∞ chains constructed from adjacent Ge(HPO4)4(OH)2 octahedra, with Cs+ cations dissociated between the chains. XRD, TGA, IR and UV–Vis–NIR absorption spectra are presented and discussed for both compounds.

scholarly journals Twisted One-Dimensional Charge Transfer and Related Y-Shaped Chromophores with a 4H-Pyranylidene Donor: Synthesis and Optical Properties

2021 ◽  
Vol 86 (4) ◽  
pp. 3152-3163
Author(s):  
Víctor Tejeda-Orusco ◽  
Raquel Andreu ◽  
Jesús Orduna ◽  
Belén Villacampa ◽  
Santiago Franco ◽  
...  
Keyword(s):  
Optical Properties ◽  
Charge Transfer ◽  
One Dimensional

Macrocyclic Se4N2[7,7]ferrocenophane and Se2N[10]ferrocenophane containing benzyl unit: synthesis, complexation, crystal structures, electrochemical and optical properties

2016 ◽  
Vol 45 (8) ◽  
pp. 3417-3428 ◽  
Author(s):  
Jian Qu ◽  
Yinglin Song ◽  
Wei Ji ◽  
Su Jing ◽  
Dunru Zhu ◽  
...  
Keyword(s):  
Optical Properties ◽  
Crystal Structures ◽  
Third Order ◽  
Conjugated Systems

Se4N2[7,7]ferrocenophane containing benzyl unit shows switch-on third-order NLO responses to Cu2+ and Hg2+ due to the formation of delocalized π-conjugated systems.

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