The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: No classical C–H activation, but efficient C–H functionalization

2006 ◽  
pp. 5559-5566 ◽  
Author(s):  
M. Mar Díaz-Requejo ◽  
Tomás R. Belderrain ◽  
M. Carmen Nicasio ◽  
Pedro J. Pérez
Keyword(s):  
Carbene Insertion ◽  
Catalytic Functionalization

The Mechanism of the Catalytic Functionalization of Haloalkanes by Carbene Insertion: An Experimental and Theoretical Study

2009 ◽  
Vol 28 (20) ◽  
pp. 5968-5981 ◽  
Author(s):  
Juan Urbano ◽  
Ataualpa A. C. Braga ◽  
Feliu Maseras ◽  
Eleuterio Álvarez ◽  
M. Mar Díaz-Requejo ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Carbene Insertion ◽  
Catalytic Functionalization

scholarly journals Organocatalytic Asymmetric Synthesis of α-Amino Esters from Sulfoxonium Ylides

2021 ◽  
Author(s):  
Wengang Guo ◽  
Hai Huang ◽  
Jianwei Sun
Keyword(s):  
Asymmetric Synthesis ◽  
Insertion Reaction ◽  
Metal Catalyst ◽  
Insertion Reactions ◽  
Amino Esters ◽  
Carbene Insertion

Described here is the first organocatalytic asymmetric N−H insertion reaction of α-carbonyl sulfoxonium ylides. Without a metal catalyst, this reaction represents an attractive complement to the well-established carbene insertion reactions....

Engineering of RuMb: Toward a Green Catalyst for Carbene Insertion Reactions

2017 ◽  
Vol 56 (10) ◽  
pp. 5623-5635 ◽  
Author(s):  
Matthew W. Wolf ◽  
David A. Vargas ◽  
Nicolai Lehnert
Keyword(s):  
Insertion Reactions ◽  
Green Catalyst ◽  
Carbene Insertion
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