Cryovoltammetrically probing functional group reductive cleavage: alkyl–sulfur versus aryl–sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable

2006 ◽  
pp. 3402-3404 ◽  
Author(s):  
Christopher A. Paddon ◽  
Farrah L. Bhatti ◽  
Timothy J. Donohoe ◽  
Richard G. Compton
Keyword(s):  
Electron Transfer ◽  
Functional Group ◽  
Bond Cleavage ◽  
Reductive Cleavage ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Sulfur Bond

Palladium-mediated radical homocoupling reactions: a surface catalytic insight

2018 ◽  
Vol 8 (18) ◽  
pp. 4766-4773 ◽  
Author(s):  
Isabelle Favier ◽  
Marie-Lou Toro ◽  
Pierre Lecante ◽  
Daniel Pla ◽  
Montserrat Gómez
Keyword(s):  
Electron Transfer ◽  
Metal Surface ◽  
Functional Group ◽  
Single Electron ◽  
Mechanistic Study ◽  
Single Electron Transfer ◽  
Palladium Nanoparticle ◽  
Transfer Processes ◽  
Electron Transfer Processes ◽  
Reductive Homocoupling

In this work, we report a palladium nanoparticle-promoted reductive homocoupling of haloarenes, exhibiting a broad functional group tolerance. A mechanistic study was carried out, suggesting single-electron transfer processes on the metal surface.

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