Single Electron Transfer-Mediated Selectiveendo- andexocyclic Bond Cleavage Processes in Azaphosphiridine Chromium(0) Complexes: A Computational Study

2012 ◽  
Vol 51 (13) ◽  
pp. 7250-7256 ◽  
Author(s):  
Arturo Espinosa ◽  
Celia Gómez ◽  
Rainer Streubel
Keyword(s):  
Electron Transfer ◽  
Computational Study ◽  
Bond Cleavage ◽  
Single Electron ◽  
Single Electron Transfer

scholarly journals Visible-Light-Mediated Photocatalytic Oxidative C–C Bond Cleavage of Geminal Diazides: An Approach to Oxamates

SynOpen ◽  
2021 ◽  
Vol 05 (02) ◽  
pp. 152-157
Author(s):  
Duddu S. Sharada ◽  
Narenderreddy Katta ◽  
Arumugavel Murugan ◽  
Sonika Sharma
Keyword(s):  
Electron Transfer ◽  
Visible Light ◽  
Bond Cleavage ◽  
Organic Dye ◽  
Single Electron ◽  
Mechanistic Study ◽  
Single Electron Transfer ◽  
Photoredox Catalysis ◽  
The Past ◽  
Remarkable Progress

AbstractPhotoredox catalysis has received great attention in both academia and industry and remarkable progress has been made over the past decade. Now, it has been shown that a visible-light-mediated oxidative C–C bond cleavage of geminal diazides can be induced by organic dye catalysis for the synthesis of oxamates. A mechanistic study, confirmed by control experiments, indicates that this proceeds through single-electron transfer (SET). This methodology can be applied to convert a wide array of geminal diazides into oxamates.

Photoinduced transition-metal and external photosensitizer free cross-coupling of aryl triflates with trialkyl phosphites

2021 ◽  
Author(s):  
Qian Dou ◽  
Li Geng ◽  
Bin Cheng ◽  
Chao-Jun Li ◽  
Huiying Zeng
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Bond Cleavage ◽  
Cross Coupling ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Rearrangement Process ◽  
Trialkyl Phosphites

Photoinduced phosphonation of aryl triflates with trialkyl phosphites via a tandem single-electron-transfer, C–O bond cleavage and Arbuzov rearrangement process in the absence of transition-metal and external photosensitizer is reported herein....

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