Flash-photolytic generation of dienols and dienolates from α,β-unsaturated esters and kinetics of their amine-catalyzed ketonization in nonaqueous media

2006 ◽  
Vol 5 (4) ◽  
pp. 426 ◽  
Author(s):  
Françoise Hénin ◽  
Stéphane Létinois ◽  
Jacques Muzart ◽  
Jakob Wirz
Keyword(s):  
Nonaqueous Media ◽  
Unsaturated Esters ◽  
Kinetics Of

Influence of medium on alkaline hydrolysis of succinic acid monomethyl and monopropyl esters

1980 ◽  
Vol 45 (11) ◽  
pp. 2873-2882
Author(s):  
Vladislav Holba ◽  
Ján Benko
Keyword(s):  
Succinic Acid ◽  
Kinetic Parameters ◽  
Alkaline Hydrolysis ◽  
Specific Interactions ◽  
Nonaqueous Media ◽  
The Media ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of alkaline hydrolysis of succinic acid monomethyl and monopropyl esters were studied in mixed aqueous-nonaqueous media at various temperatures and ionic strengths. The results of measurements are discussed in terms of electrostatic and specific interactions between the reactants and other components of the reaction mixture. The kinetic parameters in the media under study are related to the influence of the cosolvent on the solvation sphere of the reactants.

Kinetics of 1-(2-phenylethyl)-4-phenylaminopiperidine acylation by propionyl chloride in nonaqueous media

2010 ◽  
Vol 44 (5) ◽  
pp. 261-264
Author(s):  
U. A. Murashova ◽  
L. V. Skalkina ◽  
E. N. Glukhan ◽  
S. K. Smirnov
Keyword(s):  
Nonaqueous Media ◽  
Propionyl Chloride ◽  
Kinetics Of
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