Nanocast mesoporous MgAl2O4spinel monoliths as support for highly active gold CO oxidation catalyst

2006 ◽  
pp. 1772-1774 ◽  
Author(s):  
Wen-Cui Li ◽  
Massimiliano Comotti ◽  
An-Hui Lu ◽  
Ferdi Schüth
Keyword(s):  
Co Oxidation ◽  
Oxidation Catalyst ◽  
Highly Active

scholarly journals Preparation, Characterization and CO Oxidation Performance of Ag2O/γ-Al2O3 and (Ag2O+RuO2)/γ-Al2O3 Catalysts

Surfaces ◽  
2020 ◽  
Vol 3 (2) ◽  
pp. 251-264
Author(s):  
Antony Ananth ◽  
Rak Hyun Jeong ◽  
Jin-Hyo Boo
Keyword(s):  
Co Oxidation ◽  
Catalyst Support ◽  
Ruthenium Oxide ◽  
Catalytic Performance ◽  
Oxidation Catalyst ◽  
Pore Characteristics ◽  
Good Thermal Stability ◽  
Composite Catalysts ◽  
Highly Active ◽  
Temperature Programmed

This research dealt with the preparation and characterization of silver oxide (SLO) nanomaterials (NMs) and their composite catalysts (i.e., silver and ruthenium oxide (SLORUO)). The prepared materials were tested for their catalytic performance in carbon monoxide (CO) oxidation. Generally, silver in its pure state is not widely used for CO oxidation due to stability and structural issues. However, the usage of subsurface oxygen and oxygen-induced reconstruction could be effective as an oxidation catalyst at a slightly high temperature. The low-temperature reaction of highly active RuO2 (RUO) is a well-known phenomenon. Thus, the possibility of using it with SLO to observe the combined catalytic behavior was investigated. The wet chemically prepared SLO and SLORUO NMs exhibited spherical and rods in spherical aggregate-type surface morphology belonging to cubic and rutile crystalline structures, respectively. The NMs and catalysts (i.e., the NMs on γ-Al2O3 catalyst support at 0.5 and 1.0 wt.% ranges) showed good thermal stability. The dry and wet CO oxidation using RUO and SLO showed concentration-dependent catalytic activity. The RUO, SLO, and SLORUO composites using 0.5 wt.% showed full CO oxidation at 200, 300, and 225 °C, respectively. The reasons for the observed activity of the catalysts are explained based on the pore characteristics, chemical composition, and dispersion using H2 temperature-programmed reduction (TPR) behaviors.

scholarly journals Alumina-supported sub-nanometer Pt10 clusters: amorphization and role of the support material in a highly active CO oxidation catalyst

2017 ◽  
Vol 5 (10) ◽  
pp. 4923-4931 ◽  
Author(s):  
Chunrong Yin ◽  
Fabio R. Negreiros ◽  
Giovanni Barcaro ◽  
Atsushi Beniya ◽  
Luca Sementa ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Oxidation Catalyst ◽  
Support Material ◽  
Highly Active

Bridging the support gap in heterogeneous ultrananocatalysis.

scholarly journals Facet-Dependent Reactivity of Ceria Nanoparticles Exemplified by CeO2-Based Transition Metal Catalysts: A Critical Review

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 452
Author(s):  
Michalis Konsolakis ◽  
Maria Lykaki
Keyword(s):  
Transition Metal ◽  
Co Oxidation ◽  
Critical Review ◽  
Rational Design ◽  
Metal Catalysts ◽  
Co2 Hydrogenation ◽  
Transition Metal Catalysts ◽  
Fine Tuning ◽  
Ceria Nanoparticles ◽  
Highly Active

The rational design and fabrication of highly-active and cost-efficient catalytic materials constitutes the main research pillar in catalysis field. In this context, the fine-tuning of size and shape at the nanometer scale can exert an intense impact not only on the inherent reactivity of catalyst’s counterparts but also on their interfacial interactions; it can also opening up new horizons for the development of highly active and robust materials. The present critical review, focusing mainly on our recent advances on the topic, aims to highlight the pivotal role of shape engineering in catalysis, exemplified by noble metal-free, CeO2-based transition metal catalysts (TMs/CeO2). The underlying mechanism of facet-dependent reactivity is initially discussed. The main implications of ceria nanoparticles’ shape engineering (rods, cubes, and polyhedra) in catalysis are next discussed, on the ground of some of the most pertinent heterogeneous reactions, such as CO2 hydrogenation, CO oxidation, and N2O decomposition. It is clearly revealed that shape functionalization can remarkably affect the intrinsic features and in turn the reactivity of ceria nanoparticles. More importantly, by combining ceria nanoparticles (CeO2 NPs) of specific architecture with various transition metals (e.g., Cu, Fe, Co, and Ni) remarkably active multifunctional composites can be obtained due mainly to the synergistic metalceria interactions. From the practical point of view, novel catalyst formulations with similar or even superior reactivity to that of noble metals can be obtained by co-adjusting the shape and composition of mixed oxides, such as Cu/ceria nanorods for CO oxidation and Ni/ceria nanorods for CO2 hydrogenation. The conclusions derived could provide the design principles of earth-abundant metal oxide catalysts for various real-life environmental and energy applications.

Redox chemistry of gold in a Au/FeO /CeO2 CO oxidation catalyst

2009 ◽  
Vol 10 (8) ◽  
pp. 1196-1202 ◽  
Author(s):  
A. Penkova ◽  
K. Chakarova ◽  
O.H. Laguna ◽  
K. Hadjiivanov ◽  
F. Romero Saria ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Redox Chemistry ◽  
Oxidation Catalyst

Highly active PdCeOx composite catalysts for low-temperature CO oxidation, prepared by plasma-arc synthesis

2014 ◽  
Vol 147 ◽  
pp. 132-143 ◽  
Author(s):  
R.V. Gulyaev ◽  
E.M. Slavinskaya ◽  
S.A. Novopashin ◽  
D.V. Smovzh ◽  
A.V. Zaikovskii ◽  
...  
Keyword(s):  
Low Temperature ◽  
Co Oxidation ◽  
Plasma Arc ◽  
Composite Catalysts ◽  
Highly Active ◽  
Low Temperature Co Oxidation

Preparation of Highly Active, Low Au-Loaded, Au/CeO2 Nanoparticle Catalysts That Promote CO Oxidation at Ambient Temperatures

2009 ◽  
Vol 114 (2) ◽  
pp. 793-798 ◽  
Author(s):  
Mingmei Han ◽  
Xiaojing Wang ◽  
Yuenian Shen ◽  
Changhe Tang ◽  
Guangshe Li ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Ambient Temperatures ◽  
Nanoparticle Catalysts ◽  
Highly Active

scholarly journals An oxidized magnetic Au single atom on doped TiO2(110) becomes a high performance CO oxidation catalyst due to the charge effect

2017 ◽  
Vol 5 (36) ◽  
pp. 19316-19322 ◽  
Author(s):  
J. L. Shi ◽  
X. J. Zhao ◽  
L. Y. Zhang ◽  
X. L. Xue ◽  
Z. X. Guo ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Co Oxidation ◽  
High Performance ◽  
Important Application ◽  
Oxidation Catalyst ◽  
Single Atom ◽  
Charge Effect ◽  
Extensive Investigation ◽  
Doped Tio2

Catalysis using gold nanoparticles supported on oxides has been under extensive investigation for many important application processes.

scholarly journals CO oxidation over Pt-modified CuO catalysts in the presence of water vapour and SO2

2015 ◽  
Vol 18 (2) ◽  
pp. 187-196
Author(s):  
Tri Nguyen ◽  
Anh Cam Ha ◽  
Loc Cam Luu ◽  
Cuong Tien Hoang ◽  
Thi Thi Yen Trinh ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Water Vapour ◽  
Co Adsorption ◽  
X Ray Diffraction ◽  
Active Centers ◽  
Highly Active ◽  
Transmission Electron ◽  
Physico Chemical ◽  
Adsorption Of Co ◽  
Temperature Programmed

The optimal Pt-modified CuO supported on γ-Al2O3 and γ-Al2O3 + CeO2 catalysts have been prepared. Physico-chemical characteristics of catalysts were investigated and determined by the methods of N2 adsorption (BET), X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), temperature-programmed reduction (TPR), and hydrogen pulse chemisorption (HPC). The characteristics of carbon monoxide (CO) adsorption on catalysts were defined by the method of infrared spectroscopy (IR) in the range of 4000 – 400 cm-1. The effect of the mixture of water vapour and SO2 on the activity of these catalysts for the CO oxidation was assessed. Reactions were conducted at 200oC and 350oC in the absence and presence of the mixture of water vapour (1.1 mol %) and SO2 (0.0625 mol %). Concentrations of O2 and CO in the gas mixture were 9.2 mol % and 0.5 mol %, respectively. The results showed that in the catalysts there exist highly active centers Cu1+ and Pt2+. On the catalysts the adsorption of CO on Cu2+, Pt2+, CeO2, and γ - Al2O3 centres was observed. Addition of CeO2 led to increase the reductivity, CO adsorption but decrease in specific surface area of catalyst. The result PtCu/CeAl catalyst shown higher active, but lower stability compared to PtCu/Al catalyst. The mixture of water vapour and SO2 showed the reversible poisoning toward the Pt-CuO catalysts at a temperature of 350oC, but irreversible at 200oC

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