Quasi-one-dimensional molecular magnets based on derivatives of (fluorobenzyl)pyridinium with the [M(mnt)2] monoanion (M = Ni, Pd or Pt; mnt2? = maleonitriledithiolate): Syntheses, crystal structures and magnetic properties

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Two heterometallic cluster {Ln8Cr4} were constructed from two classical “drum-like” {Ln4Cr2} building units associated by organic ligands HIN, displaying 1D wave chain structure. The MCE values for {Gd8Cr4} at 3 K and 7 T is 23.40 J kg−1 K−1.


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