Magnetic properties of EuS nanoparticles synthesized by thermal decomposition of molecular precursors

2005 ◽  
Vol 15 (39) ◽  
pp. 4209 ◽  
Author(s):  
Fei Zhao ◽  
Hao-Ling Sun ◽  
Song Gao ◽  
Gang Su
Keyword(s):  
Thermal Decomposition ◽  
Magnetic Properties ◽  
Molecular Precursors

EuS–CdS and EuS–ZnS heterostructured nanocrystals constructed by Co-thermal decomposition of molecular precursors in the solution phase

2015 ◽  
Vol 3 (16) ◽  
pp. 3902-3907 ◽  
Author(s):  
Xueyun Gong ◽  
Zhengqing Liu ◽  
Dong Yan ◽  
Hongyang Zhao ◽  
Na Li ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Magnetic Properties ◽  
Decomposition Method ◽  
Solution Phase ◽  
Molecular Precursors ◽  
Thermal Decomposition Method

The EuS–CdS heterostructured nanocrystals, which possess unique optical-magnetic properties, were synthesized by a co-thermal decomposition method.

Nd7,33Ta8O28CI6 — ein Zwischenprodukt des thermischen Abbaus von Nd2Ta2O7Cl2: Präparation, Struktur und magnetische Eigenschaften / Nd7,33Ta8O28Cl6 — an Intermediate Product of the Thermal Decomposition of Nd2Ta2O7Cl2: Preparation, Crystal Structure and Magnetic Properties

1988 ◽  
Vol 43 (12) ◽  
pp. 1567-1574 ◽  
Author(s):  
U. Schaffrath ◽  
R. Gruehn
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Magnetic Properties ◽  
Calculated Data ◽  
Chemical Transport ◽  
Structure Type ◽  
Magnetic Susceptibilities ◽  
Relationship Of ◽  
The Relationship ◽  
Preparative Route

Abstract Single crystals of the new oxochlorotantalate Nd7.33Ta8O28Cl6, could be obtained only by chemical transport reactions (T2 → T1; T2 - 1000 °C, T, = 900 °C) with mixtures of Cl2/TaCl5 as transport agent. NdTaO4 was chosen as the starting material. A direct preparative route to Nd7.33Ta8O28Cl6 from binary and ternary components, however, was not successful. Nd7.33Ta8O28Cl6 , crystallizes in the space group Cmmm with a = 10.3381(8) Å, b = 18.865(1) Å, c - 3.9152(3) A; Z = 1. The structure was refined to R - 4.42%, R w = 2.76%. Main building units are pairs of edge-sharing TaO6 -octahedra which are connected with threefold capped trigonal prisms around Nd. Especially remarkable is one Nd position with an occupation factor of 0.833. The relationship of this new structure type with Nd2Ta2O7Cl2 is considered. Furthermore, we have measured the magnetic susceptibilities of both Nd-compounds in a temperature range from 3,6 to 251,3 K. The results are compared with calculated data.

scholarly journals Spin Cross-Over (SCO) Complex Based on Unsymmetrical Functionalized Triazacyclononane Ligand: Structural Characterization and Magnetic Properties

2019 ◽  
Vol 5 (1) ◽  
pp. 19 ◽  
Author(s):  
Merzouk Halit ◽  
Mélissa Roger ◽  
Véronique Patinec ◽  
Said Yefsah ◽  
Carlos Gómez-García ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Magnetic Properties ◽  
Nmr Spectroscopy ◽  
Functional Groups ◽  
Structural Characterization ◽  
Spin Crossover ◽  
Magnetic Studies ◽  
Dsc Measurements ◽  
Hexadentate Ligand

The unsymmetrical ligand 1-(2-aminophenyl)-4,7-bis(pyridin-2-ylmethyl)-1,4,7-triazacyclononane (L6) has been prepared and characterized by NMR spectroscopy. The L6 ligand is based on the triazamacrocycle (tacn) ring that is functionalized by two flexible 2-pyridylmethyl and one rigid 2-aminophenyl groups. Reaction of this ligand with Fe(ClO4)2·xH2O led to the complex [Fe(L6)](ClO4)2 (1), which was characterized as the first Fe(II) complex based on the unsymmetrical N-functionalized tacn ligand. The crystal structure revealed a discrete monomeric [FeL6]2+ entity in which the unsymmetrical N-functionalized triazacyclononane molecule (L6) acts as hexadentate ligand. As observed in the few parent examples that are based on the symmetrical N-functionalized tacn ligands, the triazacyclononane ring is facially coordinated and the N-donor atoms of the three functional groups (two pyridine and one aniline groups) are disposed in the same side of the tacn ring, leading to a distorted FeN6 environment. The magnetic studies of 1 revealed the presence of an incomplete spin crossover (SCO) transition above 425 K, whose progress would be prevented by a very exothermic thermal decomposition at ca. 472 K, as shown by thermogravimetric and DSC measurements.

A novel hybrid iron fluoride based on 8-hydroxyquinoline: Crystal structure, thermal decomposition, spectroscopic characterization, and magnetic properties

2019 ◽  
Vol 496 ◽  
pp. 119033
Author(s):  
Oussama Guesmi ◽  
Mohammed S.M. Abdelbaky ◽  
David Martínez-Blanco ◽  
Lilia Ktari ◽  
Santiago García-Granda ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Magnetic Properties ◽  
Spectroscopic Characterization ◽  
Iron Fluoride
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