One-step direct synthesis of a Ti-doped sodium alanate hydrogen storage material

2005 ◽  
pp. 4732 ◽  
Author(s):  
José M. Bellosta von Colbe ◽  
Michael Felderhoff ◽  
Borislav Bogdanović ◽  
Ferdi Schüth ◽  
Claudia Weidenthaler
ChemInform ◽  
2005 ◽  
Vol 36 (51) ◽  
Author(s):  
Jose M. Bellosta von Colbe ◽  
Michael Felderhoff ◽  
Borislav Bogdanovic ◽  
Ferdi Schueth ◽  
Claudia Weidenthaler

2017 ◽  
Vol 6 (3) ◽  
pp. 487-500 ◽  
Author(s):  
Yongfeng Liu ◽  
Zhuanghe Ren ◽  
Xin Zhang ◽  
Ni Jian ◽  
Yaxiong Yang ◽  
...  

Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4428 ◽  
Author(s):  
Ting Wang ◽  
Kondo-Francois Aguey-Zinsou

Hydrogen is regarded as a promising energy carrier to substitute fossil fuels. However, storing hydrogen with high density remains a challenge. NaBH4 is a potential hydrogen storage material due to its high gravimetric hydrogen density (10.8 mass%), but the hydrogen kinetic and thermodynamic properties of NaBH4 are poor against the application needs. Nanosizing is an effective strategy to improve the hydrogen properties of NaBH4. In this context, we report on the direct synthesis of NaBH4 nanoparticles (~6–260 nm) from the NaOCH3 precursor. The hydrogen desorption properties of such nanoparticles are reported as well as experimental conditions that lead to the synthesis of (Na2B12H12) free NaBH4 nanoparticles.


2021 ◽  
Vol 765 ◽  
pp. 138277
Author(s):  
Pingping Liu ◽  
Yafei Zhang ◽  
Xiangjun Xu ◽  
Fangming Liu ◽  
Jibiao Li

2012 ◽  
Vol 512-515 ◽  
pp. 1438-1441 ◽  
Author(s):  
Hong Min Kan ◽  
Ning Zhang ◽  
Xiao Yang Wang ◽  
Hong Sun

An overview of recent advances in hydrogen storage is presented in this review. The main focus is on metal hydrides, liquid-phase hydrogen storage material, alkaline earth metal NC/polymer composites and lithium borohydride ammoniate. Boron-nitrogen-based liquid-phase hydrogen storage material is a liquid under ambient conditions, air- and moisture-stable, recyclable and releases H2controllably and cleanly. It is not a solid material. It is easy storage and transport. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based distribution infrastructure. An air-stable composite material that consists of metallic Mg nanocrystals (NCs) in a gas-barrier polymer matrix that enables both the storage of a high density of hydrogen and rapid kinetics (loading in <30 min at 200°C). Moreover, nanostructuring of Mg provides rapid storage kinetics without using expensive heavy-metal catalysts. The Co-catalyzed lithium borohydride ammoniate, Li(NH3)4/3BH4 releases 17.8 wt% of hydrogen in the temperature range of 135 to 250 °C in a closed vessel. This is the maximum amount of dehydrogenation in all reports. These will reduce economy cost of the global transition from fossil fuels to hydrogen energy.


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