The tailoring of crystal structures via the self-assembly of organic coordination compounds by N⋯I non-covalent halogen bonds: co-crystals of sterically hindered N-heterocycles and 1,4-diiodo-tetrafluorobenzene

CrystEngComm ◽  
2005 ◽  
Vol 7 (50) ◽  
pp. 302-308 ◽  
Author(s):  
Jean-Laurent Syssa-Magalé ◽  
Kamal Boubekeur ◽  
Pierre Palvadeau ◽  
Alain Meerschaut ◽  
Bernd Schöllhorn
Keyword(s):  
Crystal Structures ◽  
Self Assembly ◽  
Coordination Compounds ◽  
The Self ◽  
Halogen Bonds ◽  
Sterically Hindered

scholarly journals Self-Assembly of Shape-Tunable Oblate Colloidal Particles into Orientationally Ordered Crystals, Glassy Crystals and Plastic Crystals

Soft Matter ◽  
2021 ◽  
Author(s):  
Jiawei Lu ◽  
Xiangyu Bu ◽  
Xinghua Zhang ◽  
Bing Liu
Keyword(s):  
Crystal Structures ◽  
Self Assembly ◽  
Colloidal Particles ◽  
Building Blocks ◽  
Fundamental Question ◽  
The Self ◽  
Plastic Crystals ◽  
Self Assembled ◽  
Glassy Crystals ◽  
The Relationship

The shapes of colloidal particles are crucial to the self-assembled superstructures. Understanding the relationship between the shapes of building blocks and the resulting crystal structures is an important fundamental question....

scholarly journals Halogen Bonds Fabricate 2D Molecular Self-Assembled Nanostructures by Scanning Tunneling Microscopy

Crystals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1057
Author(s):  
Yi Wang ◽  
Xinrui Miao ◽  
Wenli Deng
Keyword(s):  
Scanning Tunneling Microscopy ◽  
Self Assembly ◽  
Density Functional ◽  
Deep Understanding ◽  
Halogen Bonding ◽  
The Self ◽  
Scanning Tunneling ◽  
Halogen Bonds ◽  
Tunneling Microscopy ◽  
Self Assembled

Halogen bonds are currently new noncovalent interactions due to their moderate strength and high directionality, which are widely investigated in crystal engineering. The study about supramolecular two-dimensional architectures on solid surfaces fabricated by halogen bonding has been performed recently. Scanning tunneling microscopy (STM) has the advantages of realizing in situ, real-time, and atomic-level characterization. Our group has carried out molecular self-assembly induced by halogen bonds at the liquid–solid interface for about ten years. In this review, we mainly describe the concept and history of halogen bonding and the progress in the self-assembly of halogen-based organic molecules at the liquid/graphite interface in our laboratory. Our focus is mainly on (1) the effect of position, number, and type of halogen substituent on the formation of nanostructures; (2) the competition and cooperation of the halogen bond and the hydrogen bond; (3) solution concentration and solvent effects on the molecular assembly; and (4) a deep understanding of the self-assembled mechanism by density functional theory (DFT) calculations.

Controlling the self-assembly of homochiral coordination architectures of CuII by substitution in amino acid based ligands: synthesis, crystal structures and physicochemical properties

2015 ◽  
Vol 44 (12) ◽  
pp. 5672-5687 ◽  
Author(s):  
Navnita Kumar ◽  
Sadhika Khullar ◽  
Sanjay K. Mandal
Keyword(s):  
Amino Acid ◽  
Physicochemical Properties ◽  
Crystal Structures ◽  
Self Assembly ◽  
The Self ◽  
Chiral Ligands

In this paper we report six chiral ligands based on l-tyrosine, l-serine and l-phenylalanine and their homochiral CuII complexes to study the effect of various substitutions in the ligands on the formation of diverse coordination architectures.

scholarly journals Complex Crystal Structures Formed by the Self-Assembly of Ditethered Nanospheres

Nano Letters ◽  
2009 ◽  
Vol 9 (3) ◽  
pp. 1206-1211 ◽  
Author(s):  
Christopher R. Iacovella ◽  
Sharon C. Glotzer
Keyword(s):  
Crystal Structures ◽  
Self Assembly ◽  
The Self ◽  
Complex Crystal
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