scholarly journals Complex Crystal Structures Formed by the Self-Assembly of Ditethered Nanospheres

Nano Letters ◽  
2009 ◽  
Vol 9 (3) ◽  
pp. 1206-1211 ◽  
Author(s):  
Christopher R. Iacovella ◽  
Sharon C. Glotzer
Keyword(s):  
Crystal Structures ◽  
Self Assembly ◽  
The Self ◽  
Complex Crystal

scholarly journals Self-Assembly of Shape-Tunable Oblate Colloidal Particles into Orientationally Ordered Crystals, Glassy Crystals and Plastic Crystals

Soft Matter ◽  
2021 ◽  
Author(s):  
Jiawei Lu ◽  
Xiangyu Bu ◽  
Xinghua Zhang ◽  
Bing Liu
Keyword(s):  
Crystal Structures ◽  
Self Assembly ◽  
Colloidal Particles ◽  
Building Blocks ◽  
Fundamental Question ◽  
The Self ◽  
Plastic Crystals ◽  
Self Assembled ◽  
Glassy Crystals ◽  
The Relationship

The shapes of colloidal particles are crucial to the self-assembled superstructures. Understanding the relationship between the shapes of building blocks and the resulting crystal structures is an important fundamental question....

Controlling the self-assembly of homochiral coordination architectures of CuII by substitution in amino acid based ligands: synthesis, crystal structures and physicochemical properties

2015 ◽  
Vol 44 (12) ◽  
pp. 5672-5687 ◽  
Author(s):  
Navnita Kumar ◽  
Sadhika Khullar ◽  
Sanjay K. Mandal
Keyword(s):  
Amino Acid ◽  
Physicochemical Properties ◽  
Crystal Structures ◽  
Self Assembly ◽  
The Self ◽  
Chiral Ligands

In this paper we report six chiral ligands based on l-tyrosine, l-serine and l-phenylalanine and their homochiral CuII complexes to study the effect of various substitutions in the ligands on the formation of diverse coordination architectures.

scholarly journals Interplay between Polymorphism and Isostructurality in the 2-Fur- and 2-Thenaldehyde Semi- and Thiosemicarbazones

Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 993
Author(s):  
Marcin Swiatkowski ◽  
Agata Trzesowska-Kruszynska ◽  
Agnieszka Danielewicz ◽  
Paulina Sobczak ◽  
Rafal Kruszynski
Keyword(s):  
Crystal Structures ◽  
Electron Density ◽  
Self Assembly ◽  
Crystal Packing ◽  
The Self ◽  
Polymorphic Forms ◽  
Full Interaction ◽  
Crystal Packing Effects ◽  
Packing Effects

The four compounds, namely: 5-nitro-2-furaldehyde thiosemicarbazone (1); 5-nitro-2-thiophene thiosemicarbazone (2); 5-nitro-2-furaldehyde semicarbazone (3); and 5-nitro-2-thiophene semicarbazone (4) were synthesized and crystallized. The three new crystal structures of 1, 2, and 4 were determined and compared to three already known crystal structures of 3. Additionally, two new polymorphic forms of 1 solvate were synthesized and studied. The influence of the exchange of 2-thiophene to 2-furaldehyde as well as thiosemicarbazone and semicarbazone on the self-assembly of supramolecular nets was elucidated and discussed in terms of the formed synthons and assemblies accompanied by Full Interaction Maps analysis. Changes in the strength of IR oscillators caused by the molecular and crystal packing effects are described and explained in terms of changes of electron density.

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