Molecular chairs, zippers, zigzag and helical chains: chemical enumeration of supramolecular isomerism based on a predesigned metal–organic building-block

2005 ◽  
pp. 1258-1260 ◽  
Author(s):  
Jie-Peng Zhang ◽  
Yan-Yong Lin ◽  
Xiao-Chun Huang ◽  
Xiao-Ming Chen
Keyword(s):  
Building Block ◽  
Supramolecular Isomerism ◽  
Metal Organic

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

2018 ◽  
Vol 54 (22) ◽  
pp. 2735-2738 ◽  
Author(s):  
Andrey A. Bezrukov ◽  
Karl W. Törnroos ◽  
Erwan Le Roux ◽  
Pascal D. C. Dietzel
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Molecular Building Block ◽  
Molecular Precursor ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A dimeric Zr12 oxo cluster was used as new molecular building block in construction of metal–organic frameworks utilizing the precursor approach.

A new series of Co, Ni, Zn, and Cd metal–organic architectures driven by an unsymmetrical biphenyl-tricarboxylic acid: hydrothermal assembly, structural features and properties

2018 ◽  
Vol 47 (22) ◽  
pp. 7431-7444 ◽  
Author(s):  
Jin-Zhong Gu ◽  
Yan Cai ◽  
Zi-Yue Qian ◽  
Min Wen ◽  
Zi-Fa Shi ◽  
...  
Keyword(s):  
Building Block ◽  
Coordination Compounds ◽  
Structural Features ◽  
Tricarboxylic Acid ◽  
Main Building ◽  
Metal Organic

Twelve new Zn(ii), Ni(ii), Co(ii), and Cd(ii) coordination compounds with diverse dimensionalities were assembled using 3′-nitro-biphenyl-2,4,4′-tricarboxylic acid as a main building block.

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

A polyhedral metal–organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons

2015 ◽  
Vol 51 (83) ◽  
pp. 15287-15289 ◽  
Author(s):  
Dongmei Wang ◽  
Bing Liu ◽  
Shuo Yao ◽  
Tao Wang ◽  
Guanghua Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Building Block ◽  
High Performance ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Light Hydrocarbons ◽  
Metal Organic ◽  
Organic Framework

A PMOF was assembled by the SBB strategy, which exhibited high performance for CO2capture and separation towards CO2, C2H6and C3H8over CH4.

scholarly journals Disappeared supramolecular isomer reappears with perylene guest

IUCrJ ◽  
2020 ◽  
Vol 7 (2) ◽  
pp. 324-330
Author(s):  
In-Hyeok Park ◽  
Atanu Dey ◽  
Kenta Sasaki ◽  
Masaaki Ohba ◽  
Shim Sung Lee ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Guest Molecule ◽  
Metal Organic Frameworks ◽  
Guest Molecules ◽  
Supramolecular Isomerism ◽  
The World ◽  
Different Types ◽  
Metal Organic ◽  
The Disappeared ◽  
Kinetic Form

Among different types of polymorphism, disappearing polymorphism deals with the metastable kinetic form which can not be reproduced after its first isolation. In the world of coordination polymers (CPs) and metal–organic frameworks (MOFs), despite the fact that many types of supramolecular isomerism exist, we are unaware of disappearing supramolecular isomerism akin to disappearing polymorphism. This work reports a MOF with dia topology that could not be reproduced, but subsequent synthesis yielded another supramolecular isomer, a double-pillared-layer MOF. When perylene was added in the same reaction, the disappeared dia MOF reappeared with perylene as a guest in the channels. Interestingly, the photoluminescence of the dia MOF with a perylene guest is dominated by the emission of the guest molecule. The influence of guest molecules on the stabilization of the supramolecular isomers of a MOF opens up a strategy to access MOFs with different structures.

A supermolecular building block approach for construction of chiral metal–organic frameworks

2019 ◽  
Vol 55 (59) ◽  
pp. 8639-8642 ◽  
Author(s):  
Hong Jiang ◽  
Kai-Jie Chen ◽  
Fan-Fan Zheng ◽  
Xu Chen ◽  
Yan Liu ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Metal Organic ◽  
Block Approach

Three isoreticular chiral porous metal–organic frameworks (MOFs) with different pore environments are synthesized through a supermolecular building block approach.

Planar-chiral building blocks for metal–organic frameworks

2015 ◽  
Vol 51 (23) ◽  
pp. 4796-4798 ◽  
Author(s):  
Murat Cakici ◽  
Zhi-Gang Gu ◽  
Martin Nieger ◽  
Jochen Bürck ◽  
Lars Heinke ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Chiral Building Block ◽  
Metal Organic

The first example of a planar-chiral building block being used for chiral metal–organic frameworks (MOFs) is presented.

Sign in / Sign up

Export Citation Format

Share Document